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METHOD FOR PRODUCTION OF COMPLEX NITROGEN-PHOSPHOROUS FERTILIZER

机译:氮磷复合肥的生产方法

摘要

FIELD: chemical industry, agriculture.;SUBSTANCE: invention relates to method for production of double NP-fertilizer containing 3-7 mass % of P2O5 from concentrated ammonium nitrate solution and extractive phosphoric acid solution. Starting phosphoric acid (52-54 %) is diluted with weak ammonium nitrate solution, diluted solution is additionally treated with ammonium nitrate to produce NH4NO3:P2O5 ratio in ammoniated solution not less than 3:1, wherein ammoniating is carried out simultaneously with auxiliary treatment or thereafter. Ammoniated solution is boiled down to produce residual water content of 5-20 mass % and mixed with concentrated ammonium nitrate solution. Then obtained solution is finally neutralized with ammonia, boiled down and grained. Phosphorous content in ammoniated solution is maintained preferably from 4 to 10 mass % calculated as P2O5, and as ammonium nitrate in auxiliary treatment of diluted solution preferably concentrated ammonium nitrate solution obtained by nitric acid neutralization with ammonia or 40-50 % solution obtained by conversion of calcium nitrate with ammonium carbonate is used.;EFFECT: simplified method for production of complex nitrogen-phosphorous fertilizer.;5 cl, 3 ex
机译:技术领域本发明涉及由浓硝酸铵生产含有3-7质量%的P 2 O 5 的双NP肥料的方法。溶液和萃取磷酸溶液。用稀硝酸铵溶液稀释起始磷酸(52-54%),将稀溶液再用硝酸铵处理,生成NH 4 NO 3 :P 氨化溶液中的比例为2 O 5 ,其中氨化与辅助处理同时进行或之后进行。将氨化溶液煮沸以产生5-20质量%的残留水分,并与浓硝酸铵溶液混合。然后将最终获得的溶液用氨水中和,煮沸并造粒。以P 2 O 5 计算,氨化溶液中的磷含量优选保持在4至10质量%,在稀释溶液(优选浓硝酸铵溶液)的辅助处理中以硝酸铵形式保持使用氨水中和硝酸或硝酸铵与碳酸铵转化得到的40-50%溶液制得的硝酸;效果:简化了复合氮磷肥料的生产方法; 5 cl,3 ex

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