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A method for the production of carboxylate, copolymers of monoethylenically unsaturated mono - and dicarboxylic acids as well as carboxylate rich copolymers having a low degree of neutralization

机译:一种制备羧酸盐,单烯键式不饱和一元羧酸和二元羧酸的共聚物以及中和度低的富含羧酸盐的共聚物的方法

摘要

Production of carboxylate, copolymers of monoethylenically unsaturated mono - and dicarboxylic acids having an average molecular weight mw of at least 3000 g / mol, as well as at least 20,1 w -% of the dicarboxylic acid by free radical polymerization in the presence of 2 to 19,9 molar equivalents of an organic amine, based on the total amount of all the cooh - groups of the mono - and dicarboxylic acids, in the case of a temperature of not more than 130°C. carboxylate rich copolymers having a low degree of neutralization, which are obtainable by the method, and use of such copolymers for the treatment of surfaces and as binders for fiber bonding.
机译:羧酸盐的生产,平均分子量m w 至少为3000 g / mol且单羧酸至少为20.1 w%的单烯键式不饱和一元和二元羧酸的共聚物在温度不超过130的情况下,在2至19,9摩尔当量有机胺的存在下通过自由基聚合进行反应,基于一元和二元羧酸的所有cooh-基团的总量℃。具有低中和度的富含羧酸盐的共聚物,该共聚物可通过该方法获得,并将此类共聚物用于表面处理和用作纤维粘合的粘合剂。

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