New rylene tetracarbonic acid diimide compounds useful e.g. for coloring high-molecular organic and inorganic materials; as dispersants; preparing aqueous polymer dispersions, markings and letters that absorb light from infra-red light

摘要

Rylene tetracarbonic acid diimide compounds (I) are new. Rylene tetracarbonic acid diimide compounds of formula (I) are new. R, R aH, 1-30C alkyl (whose C chain maybe interrupted by O, S, NR 1, CO and/or SO 2and is optionally substituted by CN, 1-6C alkoxy, aryl (optionally substituted with 1-18C alkyl or 1-6C alkoxy) and/or N-bound 5-9 membered heterocycle, which contains additional heteroatoms, aromatic and substituents), 5-8C cycloalkyl (whose carbon back bone is optionally interrupted by O, S and/or NR 1and optionally substituted by 1-6C alkyl), (het)aryl (optionally substituted with 1-18C alkyl, 1-6C alkoxy, CN, nitro, halo, -CONR 2R 3, -SO 2R 3and/or (het)arylazo (optionally substituted with 1-10C alkyl, 1-6C alkoxy or CN); R 1H or 1-6C alkyl; R 2, R 3H, 1-6C alkyl (optionally substituted with 1-6C alkoxy, halo, OH, COO and/or CN) or (het)aryl (substituted with alkyl and 1-6C alkyl); A : N-bound 5-9 membered ring (where the carbon back bone is optionally interrupted by O, S, NR 1and/or SO 2), 1-2 optionally saturated 4-8 membered annealed ring (where the carbon chain is optionally interrupted by the group and/or -N= and the ring system is optionally substituted with OH, nitro, NHR 2, COO, COOR 2, CONR 2R 3or NR 2R 3), 1-30C alkyl (whose carbon chain is optionally interrupted by O, S, NR 1, CO and/or SO 2and optionally substituted by CN, OH, nitro, 1-6C alkoxy, COOR 2, CONR 2R 3, aryl (optionally substituted by 1-18C alkyl or 1-6C alkoxy) and/or N-bound 5-7 membered heterocycle containing further heteroatom and aromatic and substituents), 5-8C cycloalkyl (whose carbon back bone is optionally interrupted by O, S and/or NR 1and/or optionally substituted by 1-6C alkyl), (het) aryl (optionally substituted with 1-18C alkyl, 1-6C alkoxy, CN, nitro, halo, -CONR 2R 3, -SO 2R 3and/or (het)arylazo (optionally substituted with 1-10C alkyl, 1-6C alkoxy or CN) (where m is greater than 1); X : Cl or Br (where x is greater than 1); Z : 3-20C alkyl, 3-20C alken-2-yl or 3-20C alkyn-2-yl (where the alkyl chain is optionally interrupted by O, S, NR 1, CO and/or SO 2and optionally substituted by CN, 1-6C alkoxy, COOR 2, CONR 2R 3, aryl (optionally substituted by 1-18C alkyl or 1-6C alkoxy) and/or N-bound 5-7 membered heterocycle containing further heteroatoms, aromatic and substituents), (het)aryloxy or (het)arylthio (substituted by residues of R or H) (where z is greater than 1); m : 1-2; n : 1-4 (when m is 1) or 1-6 (when m is 2); and x, z : 0-3 (when m is 1; and n+x+z is less than or equal to 4) or 0-5 (when m is 2 and n+x+z is less than or equal to 6). Independent claims are also included for the preparations of (I). [Image].