method for the manufacture of aromatic polyesters and the finished film liquid crystal line

摘要

Provided is a process for producing an aromatic liquid crystalline polyester comprising the steps of: charging into a reaction vessel 80 to 20 mol% of a compound of formula (I) and 20 to 80 mol% of a compound of formula (II): CHEM CHEM wherein R1 represents a hydrogen atom, formyl group, acetyl group, propionyl group or benzoyl group, R2 represents a hydrogen atom, methyl group, ethyl group, propyl group, benzyl group or phenyl group, the R1 groups in formulae (I) and (II) may be the same as or different from each other, and the R2 groups in formulae (I) and (II) may be the same as or different from each other; conducting a polycondensation reaction of the charged mixture at a temperature from 270 to 350 DEG C to produce an aromatic liquid crystalline polyester having a flow temperature of 210 DEG C or more and lower than the polycondensation reaction temperature by 30 DEG C or more; discharging the aromatic liquid crystalline polyester in a molten state from the reaction vessel and solidifying; then, pulverizing the solidified polyester into particles having a particle size of 3 mm or less; and heat-treating at a temperature from 200 to 310 DEG C still in the solid state under an inert gas atmosphere; wherein the flow temperature means the temperature ( DEG C) at which the melt viscosity measured by a capillary type rheometer is 48,000 poise when a resin which has been melted by heating at a temperature raising rate of 4 DEG C/min is extruded through a nozzle having an internal diameter of 1 mm and a length of 10 mm under a load of 100 kgf/cm2. The aromatic liquid crystalline polyester has improved low temperature molding processability, and the film thereof has sufficient heat-resistance and excellent gas barrier properties.