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ALUMINA CARRIER, METHOD FOR MANUFACTURING THE SAME AND HYDROGENATION/DEMETALLATION CATALYST USING THE SAME
ALUMINA CARRIER, METHOD FOR MANUFACTURING THE SAME AND HYDROGENATION/DEMETALLATION CATALYST USING THE SAME
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机译:氧化铝载体,其制造方法和使用该载体的加氢/脱金属催化剂
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摘要
PROBLEM TO BE SOLVED: To provide a hydrogenation/demetallation catalyst exhibiting high demetallation activity even when the amount of a hydrogenation-active metal component is small and to provide an alumina carrier having a specific pore structure suitable for the hydrogenation/demetallation catalyst.;SOLUTION: The alumina carrier is such an alumina molding that the specific surface area (SA) measured by a BET method based on nitrogen adsorption is within 100-250 m2/g, the total pore volume (PVT) of pores having ≥4 nm pore diameter which is measured by a mercury porosimetry is within 0.50-1.50 ml/g and the average pore diameter (PDA) corresponding to 1/2 of the total pore volume (PVT) is within 15-30 nm. The alumina molding has a first peak of a pore volume distribution within 8-20 nm pore diameter and a second peak of the pore volume distribution within 18-30 nm pore diameter. The value of the second peak is larger than that of the first peak. The pore volume (PVM) of pores having ≥100 nm pore diameter is ≤0.05 ml/g.;COPYRIGHT: (C)2007,JPO&INPIT
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机译:解决的问题:提供即使氢化活性金属成分的量少也显示高脱金属活性的氢化/脱金属催化剂,并且提供具有适合于该氢化/脱金属催化剂的特定孔结构的氧化铝载体。 :氧化铝载体是这样一种氧化铝成型体,即通过基于氮吸附的BET法测得的比表面积(SA)在100-250 m 2 Sup> / g之内,总孔体积(PV通过汞孔隙率法测得的孔径为4 nm以上的孔的Sub> T Sub>)在0.50-1.50 ml / g之内,并且平均孔径(PD A Sub>)对应于总孔体积的1/2(PV T Sub>)在15-30 nm之内。氧化铝模制品具有在8-20nm孔径内的孔体积分布的第一峰和在18-30nm孔径内的孔体积分布的第二峰。第二个峰值的值大于第一个峰值的值。孔径为100 nm以上的孔的孔体积(PV M Sub>)为≤ 0.05 ml / g 。;版权:(C)2007,JPO&INPIT
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