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Method for producing alpha, beta-unsaturated carboxylic acid ester, and alpha, beta-unsaturated carboxylic acid ester, and lubricating oil additive

机译:α,β-不饱和羧酸酯和α,β-不饱和羧酸酯的制造方法以及润滑油添加剂

摘要

A method for producing an α,β-unsaturated carboxylic acid ester is provided in which an alcohol (A) is caused to react with an α,β-unsaturated carboxylic acid or a lower alkyl ester (B) of the α,β-unsaturated carboxylic acid in the presence of a sulfonic acid group-carrying inorganic porous material (α), and an α,β-unsaturated carboxylic acid ester obtained by the above-described method is provided that contains not more than 50 ppm of sulfur atoms based on a weight of the α,β-unsaturated carboxylic acid ester, not more than 2 mol % of by-product etherification products and not more than 1 mol % of by-product addition products based on the mole number of the α,β-unsaturated carboxylic acid ester. Such methods are a method for producing an α,β-unsaturated carboxylic acid ester that does not involve generation of a large amount of waste products and a method for producing a high-purity α,β-unsaturated carboxylic acid ester that causes only a smaller amount of by-products to be generated, and a high-purity α,β-unsaturated carboxylic acid ester is provided that contains only a smaller amount of catalyst residues and exhibits less metal corrosion behavior.
机译:提供一种制备α,β-不饱和羧酸酯的方法,其中使醇(A)与α,β-不饱和羧酸或α,β-不饱和的低级烷基酯(B)反应。提供在带有磺酸基的无机多孔材料(α)存在下的羧酸,以及通过上述方法获得的α,β-不饱和羧酸酯,其包含不超过50ppm的硫原子,基于α,β-不饱和羧酸酯的重量,基于α,β-不饱和摩尔数,不超过2mol%的副产物醚化产物和不超过1mol%的副产物加成产物羧酸酯。这样的方法是不产生大量废产物的α,β-不饱和羧酸酯的制备方法,以及仅引起较小的α,β-不饱和羧酸酯的制备方法。提供了生成的大量副产物和高纯度的α,β-不饱和羧酸酯,该酯仅包含较少量的催化剂残留物,并表现出较小的金属腐蚀行为。

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