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Co- and terpolymers containing sulpho groups, soluble in water, their preparation and their use as stabilizers for aqueous building materials and paint systems and coating is based on water.

机译:含磺基的共聚物和三元共聚物,可溶于水,其制备方法以及用作水性建筑材料,涂料体系和涂料的稳定剂均基于水。

摘要

Co- and terpolymers containing sulpho, water-soluble groups with a number average molecular weight of from 50,000 to 20,000,000 g / mol, which comprises: a) from 3 to 96 mol% of structural groups of the formula I : where R 1 = hydrogen or methyl, R2, R3, R4 = hydrogen, an aliphatic hydrocarbon radical having 1 to 6 carbon atoms, a phenyl radical optionally substituted by methyl groups, V = NH or oxygen and M = hydrogen, a cation of uni- or bivalent metal, ammonium or an organic amine radical, n = 1 to 5, a = 1/2 or 1 b) from 3 to 96 mol% of structural groups of formula II: wherein W represents = -CO-O- (CH2) x-, -CO-NR2- (CH2) x-, x = represents 1 to 6, R5 and R6 represent hydrogen or an aliphatic hydrocarbon radical having 1 to 20 carbon atoms, a cycloaliphatic hydrocarbon radical having 5 to 8 carbon atoms or an aryl radical having 6 to 14 carbon atoms, optionally substituted, and R1 and R2 have the above meanings, and / or c) of 0, 05 to 75 mol% groups componentesde Formula III in which Y is O, NH or NR5 R7 = R5 respectively R6, - (CH2) x-SO3 (Ma, X = halogen, (alkyl of C1 to C4) sulfate or (alkyl C1 to C4) sulfonate and R1, R5, R6, M, a and x have the above meanings, as stabilizers for aqueous building material systems and paints and coatings are water-based.
机译:包含数均分子量为50,000至20,000,000 g / mol的磺基水溶性基团的共聚物和三元共聚物,其中包括:a)3至96 mol%的式I结构基团:其中R 1 =氢或甲基,R 2,R 3,R 4 =氢,具有1-6个碳原子的脂族烃基,任选地被甲基取代的苯基,V = NH或氧和M =氢,是一价或二价金属的阳离子,铵或有机胺基,n = 1至5,a = 1/2或1 b)3至96 mol%的式II结构基团:其中W代表= --CO-O-(CH2)x-, -CO-NR 2-(CH 2)x-,x =表示1至6,R 5和R 6表示氢或具有1至20个碳原子的脂族烃基,具有5至8个碳原子的脂环族烃基或具有碳原子数为6至14的碳原子(可选),R1和R2具有以上含义,和/或c)w为0、05至75 mol%的式III组分Y分别为O,NH或NR5 R7 = R5 R6,-(CH2)x-SO3(Ma,X =卤素,(C1至C4的烷基)硫酸盐或(C1至C4的烷基)磺酸盐,R1,R5,R6 M,a和x具有上述含义,因为用于水性建筑材料体系以及油漆和涂料的稳定剂是水基的。

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