首页> 外国专利> CATALYST FOR OLEFIN POLYMERIZATION INCLUDING PHENOXY LIGAND AND METHOD OF (CO) POLYMERIZATION OF OLEFIN USING THE SAME

CATALYST FOR OLEFIN POLYMERIZATION INCLUDING PHENOXY LIGAND AND METHOD OF (CO) POLYMERIZATION OF OLEFIN USING THE SAME

机译:包含酚醛配体的烯烃聚合催化剂和使用相同方法进行烯烃(CO)聚合的方法

摘要

The present invention provides a Ziegler-Natta catalyst for olefin polymerization comprising transition metal compound containing aryloxy ligand and transition metal with the oxidation number of 3 from Group IV, V or VI of the Periodic Table of Elements which is prepared by the reduction of transition metal compound containing at least two aryloxy ligands and transition metal with the oxidation number of 4 or more from Group IV, V or VI of the Periodic Table, and an olefin (co)polymerization method using the same as a main catalyst. According to the present invention, it is possible to provide a Ziegler-Natta catalyst for olefin polymerization having high polymerization activity, as compared with conventional catalysts of transition metal compounds comprising transition metal compound containing transition metal with the oxidation number of 3, and a method for preparing olefin (co)polymer having broad molecular weight distribution by using the same with high activity.
机译:本发明提供了一种用于烯烃聚合的齐格勒-纳塔催化剂,其包含通过还原过渡金属制备的,包含元素周期表的IV,V或VI族的氧化值为3的芳氧基配体和过渡金属的过渡金属化合物。含有至少两个芳氧基配体和元素周期表第IV,V或VI族的氧化数为4或更高的过渡金属的化合物,以及使用该化合物作为主要催化剂的烯烃(共)聚合方法。根据本发明,与包含具有3个氧化数的过渡金属的过渡金属化合物的过渡金属化合物的常规催化剂相比,可以提供具有高聚合活性的用于烯烃聚合的齐格勒-纳塔催化剂和方法。通过使用具有高活性的烯烃(共)聚合物制备具有宽分子量分布的烯烃(共)聚合物。

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