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Polyaniline Having Highly Electrical Conductivity and Process of Preparing the Same
Polyaniline Having Highly Electrical Conductivity and Process of Preparing the Same
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机译:具有高电导率的聚苯胺及其制备方法
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摘要
The invention to have a repeating structure represented by the general formula, 13 C CPMAS the characteristics of the spectrum is a peak is formed in the vicinity of 138 ppm and 143 ppm, the peak intensity (I in the 143 ppm peak intensity (I 138ppm) at 138 ppm It relates to a polyaniline and a method for producing the same, characterized in that greater than 143ppm ).; General formula ;(Wherein x and y are mole fractions of the quinonediamine structure and the methylenediamine structural unit, respectively, and satisfy 0 x 1, 0 y 1, x + y = 1).;The polyaniline synthesized according to the present invention has an electrical conductivity of up to 100 times or more compared to the conventional polyaniline and improves solubility and processability, and thus may be applied to conductive films, fibers, polymer blends, electromagnetic shielding or transparent electrodes of thin films.
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机译:本发明具有由通式 13 Sup> C CPMAS表示的重复结构,该光谱的特征是在138ppm和143ppm附近形成峰,该峰强度(I 143 ppm时的143 ppm峰值强度(I 138ppm) Sub> 它与聚苯胺及其制备方法有关,其特征在于大于 143ppm Sub >)。 通用公式 U> ;(其中x和y分别是醌二胺结构和亚甲基二胺结构单元的摩尔分数,并且满足0 <x <1,0 <y <1,x + y = 1)。根据本发明合成的聚苯胺与常规的聚苯胺相比,本发明的电导率高达100倍或更高,并且改善了溶解性和可加工性,因此本发明可以应用于导电膜,纤维,聚合物共混物,电磁屏蔽或薄膜的透明电极。
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