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METHOD FOR PREPARING POLYESTER MULTIFILAMENT YARN FOR REINFORCEMENT OF RUBBER AND POLYESTER MULTIFILAMENT YARN PREPARED BY THE SAME METHOD
METHOD FOR PREPARING POLYESTER MULTIFILAMENT YARN FOR REINFORCEMENT OF RUBBER AND POLYESTER MULTIFILAMENT YARN PREPARED BY THE SAME METHOD
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机译:用相同的方法制备用于增强橡胶的聚酯复丝纱的方法和制备的聚酯复丝纱的方法
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摘要
Disclosed is a method of producing a polyester multifilament yarn for reinforcing rubber, and a polyester multifilament yarn produced using the method. The method includes a) adding a polymerization catalyst containing 150 to 250 ppm of an antimony compound based on an antimony metal to a terephthalic acid (TPA) and ethylene glycol (EG) to perform poly¬ merization, b) solid state polymerizing a polymer obtained in step (a), c) melt spinning a solid state polymer obtained in step (b), d) winding melt spun filaments at a speed of 1500 m/min or more to produce an undrawn yarn having a density of 1.338 g/cm or more, and e) stretching the undrawn yarn obtained in step (d) to produce a polyester multifilament yarn that has intrinsic viscosity of 0.83 or more and tenacity of 8.3 g/d or more and includes 20 microequivalents/g or less of a carboxyl end group and 1.2 wt% or less of diethylene glycol. The polyester mul¬ tifilament yarn is useful as a rubber reinforcing material to produce a treated cord, such as a tire cord.
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机译:公开了一种用于增强橡胶的聚酯复丝纱线的生产方法,以及使用该方法生产的聚酯复丝纱线。该方法包括:a)向对苯二甲酸(TPA)和乙二醇(EG)中添加基于锑金属的包含150至250ppm的锑化合物的聚合催化剂以进行聚合,b)使所获得的聚合物固态聚合。在步骤(a)中,c)将在步骤(b)中获得的固态聚合物熔融纺丝,d)以1500m / min或更高的速度缠绕熔融纺丝,以产生密度为1.338g / cm的未拉伸丝e)拉伸步骤(d)中获得的未拉伸纱线,以生产特性粘度为0.83以上且韧度为8.3 g / d以上且包含20微当量/ g羧基的聚酯复丝端基和1.2wt%或更少的二甘醇。聚酯乳化纱可用作橡胶增强材料以生产经处理的帘线,例如轮胎帘线。
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