SELECTIVE INSECTICIDES BASED ON HALOALKYLNICOTINIC ACID DERIVATIVES, ANTHRANILIC ACID DERIVATIVES, OR PHTHALIC ACID DERIVATIVES AND SAFENERS

摘要

Compositions contain (A) haloalkyl-nicotinic acid derivative(s) (I), phthalic acid diamide derivative(s) (II) or anthranilamide derivative(s) (III) and (B) safener(s) selected from about 60 specific compounds (e.g. cloquintocet-mexyl, isoxadifen-ethyl, fenclorim or mefenpyr-diethyl) and 4 general classes of azole, quinoline, alkanamide or N-(phenylsulfonyl)-benzamide compounds (IVa)-(IVd). Compositions comprise: (1) at least one haloalkyl-nicotinic acid derivative of formula (I), phthalic acid diamide derivative of formula (II) or anthranilamide derivative of formula (III) (optionally in N-oxide or salt form) as active agent (A); and (2) at least one safener (B) selected from e.g. azole derivatives of formula (IV-a), quinoline derivatives of formula (IV-b), alkanamides of formula R 10d-CO-NR 11dR 12d (IV-c) and N-(phenylsulfonyl)-benzamide compounds of formula (IV-d). A aC(W a)-NR 2aR 3a, C(W a)-N=SR 9aR 10a or Het; R 1ahaloalkyl; R 2a, R 3ae.g. U-cycloalkyl (optionally substituted (os) by R 4a or Q a), C(X a)-Y a; or CH 2-heterocyclyl (os by R 5a); or NR 2aR 3ae.g. heteroaryl os by R 4a, U' or Q a; Q ahydrazono (os); R 4ae.g. S(O) n-U'; X a, W aO or S; Y ae.g. R 6a or NR 7aR 8a; R 6ae.g. -U-cycloalkyl (os); R 7ae.g. U-cycloalkyl (os); R 8ae.g. aryl (os by R 5a); R 9a, R 10ae.g. C(X a)-Y a; or R 9aR 10aheterocycle; Het : e.g. heterocycle os by R 4a, U' or Q a; X be.g. haloalkoxy; R 1b-R 3be.g. M 1b-Q b; or R 1b+R 2be.g. complete ring; M 1be.g. os alkylene; Q be.g. T b-R 4b; T be.g. S(O) m or N(R 5b); R 4be.g. T-heteroaryl (os); R 5be.g. CO-O-T-Ph (os); k : 1-4; m : 0-2; L 1b, L 3be.g. S(O) m-U; L 2be.g. M 2b-R 6b; or L 1b+L 3be.g. complete ring; M 2be.g. S(O) m; R 6be.g. heteroaryl (os); A 1c, A 2ce.g. S; X ce.g. CR 10c; R 1ce.g. V (os by R 6c or R 11c); R 2ce.g. H; R 3ce.g. R 11c or heteroaryl (os by 1-3 W c or R 12c)); or R 2c+R 3ccomplete ring M c; R 4ce.g. OT' (os); R 5c, R 8ce.g. G c, J c or S(O) p-Ph (all os by e.g. V (os by e.g. Ph (os by W or R 12c))); G ce.g. carbocycle; J ce.g. heteroaryl (os); R 6ce.g. C(E c)-R 19c, OP(Q c)(OR 19c) 2, SO 2L cR 18c or L cSO 2L cR 19c; E 1ce.g. NR 19c; R 7ce.g. SO 2T'; R 9ce.g. halo; R 10ce.g. T'; R 11e.g. phenylsulfenyl (os by W c, S(O) n(R 16c) 2 or S(O) nNR 13cSO 2L cR 14c); L ce.g. NR 18c; R 12ce.g. B(OR 17c) 2; Q cO or S; R 13ce.g. V (os); R 14ce.g. Cyc (os by e.g. R 6); R 15cU' (os by e.g. SOT' or Ph (os by 1-3 W c or R 12c); R 16ce.g. haloalkyl; or N(R 15c) 2 or N(R 16c) 2M c; R 17ce.g. T; R 18ce.g. U'; or NR 13cR 18cM c; R 19ce.g. U (os) M ce.g. ring W ce.g. T; n : 0 or 1; p : 0-2; A 12group of formula (a)-(c); r, s : 0-5; A 11de.g. N; A 2de.g. alkanediyl (os); R 8de.g. NT 2; R 9de.g. NT 2; R 10dT (os); R 11d, R 12de.g. V (os); or R 11d+R 12de.g. alkanediyl; R 13d, R 15de.g. halo; R 14de.g. U (os); X 1de.g. T'; X 2d, X 3de.g. H; Q : N(R 17d)-COR 18d or CO-NR 19dR 20d; t : 0-5; v : 0-4; R 16d, R 17de.g. T; R 18de.g. NT 2 (os); R 19de.g. U (os); R 20de.g. phenyl (os by e.g.T' or OT'); or R 19d+R 20de.g. 3-6C alkanediyl ( os); X 4d, X 5de.g. T'; T : 1-4C alkyl, U : 1-6C alkyl; T' : T or 1-4C haloalkyl; U' : U or 1-6C haloalkyl; V : 2-6C alkenyl or 2-6C alkynyl; Cyc : 3-6C cycloalkyl; and with provisos. Full Definitions are given in Definitions (Full Definitions) Field. An independent claim is included for controlling insects and/or acarina, involving applying the composition to insects and/or acarina and/or their habitat. [Image] [Image] [Image] [Image] ACTIVITY : Insecticide; acaricide; safener; nematocide. In pre-tests for control of Aphis gosspii aphids on cotton plants, mortality after 2 days was 0% using 120 g/ha N-cyanomethyl-4-trifluoromethyl-nicotinamide (flonicamid) (A'), 0% using 50 g/ha isoxadifen-ethyl (B') and 50% using a combination of 120 g/ha (A') and 50 g/ha (B'). MECHANISM OF ACTION : None given.