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Production method of Lithium containing reagent and for reducing gases in syngas produced from the gasification of waste plastics

机译:含锂试剂和还原废塑料气化生产合成气中气体的方法

摘要

The present invention is a technique for purifying synthesis gas produced by gasification of the waste, one of the flammable waste treatment method relates to, and more particularly to remove hydrogen sulfide and carbon dioxide contained in the synthesis gas by the addition of a chloride and a carbonate for enhanced adsorption capacity after the zirconia supported on the honeycomb was converted to the lithium zirconate and lithium carbonate by heat treatment at a high temperature co-carbonate relates to a method for producing the composite oxide reaction. Conventional methods include a dry processing method and a method using a liquid absorbent for absorption treatment using a solution of the amine-based hydrogen sulfide and carbon dioxide. However, in the case of a wet treatment by lowering the processing temperature to room temperature region to be processed, and then re-heated again disadvantage to have, and has the problem that the adsorption capacity of the adsorbent for dry-adsorption treatment and increase the amount of carbon monoxide required low, the hydrogen sulfide gas absorption, such as hydrogen, carbon dioxide absorption and to proceed at the same time. Therefore, the reaction for synthesis gas purification, which can more effectively utilize the synthesis gas produced by the gasification reaction by selectively removing the hydrogen sulfide and carbon dioxide by the direct reaction agent prepared lithium composite oxide without lowering the temperature in the high temperature more than 500 relates to a process for the production of.
机译:本发明是一种净化由废物气化产生的合成气的技术,其中一种可燃废物处理方法涉及,更具体地讲,是通过添加氯化物和氯化氢来除去合成气中所含的硫化氢和二氧化碳。通过在高温下碳酸氢盐热处理将蜂窝状载体上的氧化锆转化为锆酸锂和碳酸锂后,用于增强吸附能力的碳酸盐涉及一种生产复合氧化物反应的方法。常规方法包括干法处理方法和使用液体吸收剂进行吸收处理的方法,所述吸收剂使用胺基硫化氢和二氧化碳的溶液进行吸收处理。然而,在通过将处理温度降低至要处理的室温区域然后再加热的湿处理的情况下,具有缺点,并且具有干吸附处理用吸附剂的吸附容量增加的问题。一氧化碳的需要量低,硫化氢气体的吸收,如氢气吸收和二氧化碳吸收要同时进行。因此,在不降低高温下的温度的情况下,通过直接反应剂制备的锂复合氧化物选择性地除去硫化氢和二氧化碳,可以更有效地利用由气化反应产生的合成气的合成气净化反应。 500涉及一种生产方法。

著录项

  • 公开/公告号KR100703465B1

    专利类型

  • 公开/公告日2007-04-03

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20050072652

  • 发明设计人 유경선;박주원;한춘;강동환;

    申请日2005-08-09

  • 分类号B01D39/20;B01D53/00;

  • 国家 KR

  • 入库时间 2022-08-21 20:32:32

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