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Method for preparing of optically pure R-form or S-form tetrahydro furfuryl alcohol using heterogeneous catalysts

机译:使用非均相催化剂制备光学纯的R型或S型四氢糠醇的方法

摘要

The present invention is optically pure (R) using a heterogeneous catalyst in the presence of a foam-tetrahydro fur relates to a method for manufacturing a furyl alcohol (Tetrahydrofurfuryl alcohol), more specifically, a heterogeneous catalyst and an organic solvent - form or (S) (R) - form or (S) - form 2-tetrahydrofuran-acid ester (tetrahydro-2-furoic acid ester) the optically pure (R) was reduced via hydrogenation - form or (S) - tetrahydro-form It relates to a method for producing a fur-furyl alcohol. According to the invention, it can provide a clean technology that can maintain a high optical purity in a continuous hydrogenation reaction applying the heterogeneous catalyst. In addition, the manufacturing method according to the present invention is a simple process, yet excludes the extraction process is environmentally friendly process does not use toxic substances, increased production efficiency per hour has a mass production is easy due to the economic advantage on an industrial scale it is. ; (R) - tetrahydro-Fur furyl alcohol, (S) - tetrahydro-Fur furyl alcohol, 2-tetrahydrofuran ester, optically active, heterogeneous catalyst, hydrogenated
机译:本发明是在泡沫-四氢呋喃存在下使用非均相催化剂的光学纯的(R),涉及一种制造呋喃醇(四氢糠醇)的方法,更具体地讲,是非均相催化剂和有机溶剂的形式或S)(R)-型或(S)-型2-四氢呋喃酸酯(四氢-2-糠酸酯)的光学纯(R)通过氢化-型或(S)-四氢型被还原制备糠基糠醇的方法。根据本发明,可以提供一种清洁技术,该清洁技术可以在应用多相催化剂的连续氢化反应中保持高光学纯度。另外,根据本发明的制造方法是简单的过程,但是排除了提取过程是不使用有毒物质的环境友好的过程,由于工业上的经济优势,每小时的生产效率提高易于批量生产。规模是。 ; (R)-四氢呋喃糠醇,(S)-四氢呋喃糠醇,2-四氢呋喃酯,光学活性,非均相催化剂,氢化

著录项

  • 公开/公告号KR100774627B1

    专利类型

  • 公开/公告日2007-11-08

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20020064817

  • 发明设计人 임종호;고기호;곽병성;

    申请日2002-10-23

  • 分类号C07D307/12;

  • 国家 KR

  • 入库时间 2022-08-21 20:31:07

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