首页> 外国专利> Method, useful to protect metallic surface with corrosion inhibitor composition coating comprises applying coating on metallic surface, where the components comprising: deposit substance; and further components and/or matrix substance

Method, useful to protect metallic surface with corrosion inhibitor composition coating comprises applying coating on metallic surface, where the components comprising: deposit substance; and further components and/or matrix substance

机译:用于用腐蚀抑制剂组合物涂层保护金属表面的方法包括在金属表面上施加涂层,其中的组分包括:沉积物质;和和其他成分和/或基质物质

摘要

Method for the protection of metallic surface (A) with a coating (A1) of corrosion inhibitor composition, comprises applying (A1) on (A), where a component optionally at least partially in a matrix comprising: at least a deposit substance (a) comprising incorporating anions by an oxidation reaction and releasing at least a part of anions for a potential variation; and optionally at least a further components and/or matrix substance. Method for the protection of metallic surface (A) with a coating (A1) of corrosion inhibitor composition, that after providing, optionally drying and hardening, comprises applying (A1) on (A), that as a component optionally at least partially in a matrix comprising: (a) at least deposit substance and at least a conductive polymer, comprising (1) anions incorporated by an oxidation reaction as doped ion and (2) releasing at least a part of anions for a potential variation (reduction), where at least a type of anions is suitable to inhibit an anodic and/or cathodic part reaction of the corrosion and optionally also to act as coupling agent, where the anions respectively exhibits ionic radius, that it is non- or not substantially- impaired the migration through the deposit substances and optionally through at least a further component e.g. in a matrix of the coating, where at least a type of anion are mobile in water, at least an another polar solvent and/or also in at least non polar solvent containing mixture, where the release of anions from at least a deposit substance does not and/or only dependent over a deprotonation reaction, but predominantly and/or completely takes place over a reduction reaction, and where at least a educt for the preparation of the deposit substance is selected, that the oxidation potential is less or same to the decomposition potential of the water and/or at least an another polar solvents in the mixture; and (b) optionally at least a further component and/or at least a matrix substance, that at least a deposit substance serves at least partially as matrix and at least an organic polymer/copolymer, where at least a deposit substance present in the undistributed areas of the coating are at least partially oxidized and/or at least partially doped by the anions and at least the deposit substance in the disturbed areas of the at least partially reduced coating and/or devoid at least partially of doping anions, where the coating is adjusted by the contained components or their contents, that an essential content of corrosion protecting anion and optionally also of coupling agent anion is released from at least a deposit substance with a potential reduction between the redox potential at least a deposit substance in undistributed condition to the corrosion potential of the metallic surface at an defect like e.g. at an scratch or at a pollution at the boundary area metal/coating, so that it acts at least partially prematurely or prematurely against the generation and/or progression of the delamination, before the strong delamination enters at the boundary area metal/coating. Independent claims are also included for: (1) a metallic substrate with at least a coating, which is protected; and (2) use of respectively at least a complex fluoride, a titanate and/or a zirconate as an anion for at least a conductive polymer.
机译:用腐蚀抑制剂组合物的涂层(A1)保护金属表面(A)的方法,包括在(A)上施加(A1),其中组分任选至少部分地在包含至少一种沉积物质(a)的基质中)包括通过氧化反应结合阴离子并释放至少一部分阴离子以引起电势变化;以及任选地至少其他组分和/或基质物质。用腐蚀抑制剂组合物的涂层(A1)保护金属表面(A)的方法,该方法在提供,可选地干燥和硬化之后,包括在(A)上施加(A1),其作为组分至少部分地在(A)中该基质包含:(a)至少沉积物质和至少一种导电聚合物,包括(1)通过氧化反应作为掺杂离子掺入的阴离子和(2)释放至少一部分阴离子以进行电位变化(还原),其中至少一种阴离子适合于抑制腐蚀的阳极和/或阴极部分反应,并且任选地还用作偶联剂,其中所述阴离子分别具有离子半径,即其不损害或基本不损害迁移。通过沉积物质,并可选地通过至少其他组分,例如在涂层的基质中,其中至少一种阴离子在水中,至少另一种极性溶剂中和/或在至少非极性溶剂的混合物中是可移动的,其中阴离子从至少一种沉积物质中释放出来不和/或仅取决于去质子反应,而是主要和/或完全在还原反应上进行,并且在至少选择用于制备沉积物的离析物的情况下,氧化电位小于或等于混合物中水和/或至少另一种极性溶剂的分解势; (b)任选地至少另一种组分和/或至少一种基质物质,其中至少一种沉积物质至少部分地充当基质和至少一种有机聚合物/共聚物,其中至少一种沉积物质存在于未分布的物质中在至少部分还原的涂层的扰动区域和/或至少部分没有掺杂阴离子的情况下,涂层的区域至少部分地被阴离子和/或至少部分地被阴离子和至少沉积物所掺杂。通过所含组分或其含量的调节,从至少一种沉积物质中释放出防腐蚀阴离子和任选的偶联剂阴离子的基本含量,并且在未分布状态下至少一种沉积物质的氧化还原电势与金属表面在诸如在边界层金属/涂层处出现划痕或污染时,它会在强剥离作用进入边界层金属/涂层之前至少部分地过早或过早地对抗分层的产生和/或进行。还包括以下方面的独立权利要求:(1)具有至少一层被保护的金属基材; (2)分别使用至少一种复合氟化物,钛酸酯和/或锆酸酯作为至少一种导电聚合物的阴离子。

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