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The catalyst system to produce polymers having a broad molecular weight distribution and how to create the same as those

机译:制备具有宽分子量分布的聚合物的催化剂体系以及如何与之形成相同的聚合物

摘要

Cocatalyst containing non-transition metal cyclopentadienyl unsubstituted or substituted and chromium (Cp) compound is included in the catalyst system during the polymerization of olefins. The catalyst also comprises an inorganic oxide support. Methods of preparing the catalyst comprises contacting the non-transition metal Cp compound and the chromium and support. The support may be contacted with the solution containing the non-transition metal Cp compound prior to entering the reaction zone. Contact with a co-catalyst containing a non-transition metal Cp catalyst and containing chromium and the olefin include a method of polymerizing olefins at least one. The polymerization can be carried out in the presence of hydrogen. The use of the cocatalyst together with the catalyst, to improve some of the properties of such polymers to be produced in this way. Polymer composition such as produced by the method comprising greater than 30 PDI, has the unique characteristic of the various.
机译:在烯烃聚合期间,催化剂体系中包含未取代或未取代的含非过渡金属环戊二烯基和铬(Cp)化合物的助催化剂。该催化剂还包含无机氧化物载体。制备催化剂的方法包括使非过渡金属Cp化合物与铬和载体接触。载体可以在进入反应区之前与含有非过渡金属Cp化合物的溶液接触。与包含非过渡金属Cp催化剂并且包含铬的助催化剂和烯烃的接触包括聚合至少一种烯烃的方法。聚合可以在氢存在下进行。助催化剂与催化剂一起使用,以改善以这种方式生产的这种聚合物的某些性能。诸如通过包含大于30 PDI的方法生产的聚合物组合物具有各种的独特特征。

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