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Processes for singlet oxygen generation and fullerene oxidation
Processes for singlet oxygen generation and fullerene oxidation
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机译:单线态氧生成和富勒烯氧化的方法
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摘要
Powdery fullerene is milled in an oxygen atmosphere, whereby mechanical impacts are applied to the fullerene and a carbon cage of the fullerene is dynamically distorted to the extent that an energy for conversion of atmospheric oxygen to a singlet excited state is accomplished from the distorted carbon cage to atmospheric oxygen. Singlet oxygen, i.e. an efficient oxidant in various industrial fields, is generated by solid-state reaction under stable conditions without necessity of photo-irradiation. The singlet oxygen also enables efficient oxidation of fullerene itself.
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