PROCESS FOR PRODUCING HYDROGEN WITH PERMSELECTIVE MEMBRANE REACTOR AND PERMSELECTIVE MEMBRANE REACTOR

摘要

A method for producing hydrogen including the steps of supplying a raw material gas from a gas inlet of a reactor tube; producing a gas mixture containing hydrogen, carbon monoxide, and carbon dioxide by a reforming reaction and a shift reaction; recovering, from a discharge outlet of a separator tube, hydrogen being isolated by passing through a permselective membrane into the separator tube from the gas mixture; and discharging other gas components incapable of passing through the permselective membrane from a gas outlet of the reactor. Hydrogen is produced under conditions where α defined by the following equation is in the range of 0.4 to 100:; α={(CO₂)/(CO)²}/Kwherein (CO₂) and (CO) denote the partial pressures of carbon dioxide and carbon monoxide at the gas outlet and K denotes the equilibrium constant of the disproportionation reaction of carbon monoxide at the internal temperature of the reactor tube.