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Reprocessing method by fluoride volatility process using fractional distillation
Reprocessing method by fluoride volatility process using fractional distillation
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机译:分馏法氟化物挥发法的后处理方法
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摘要
Fluorine or a fluorine compound is subjected to a reaction with a spent oxide fuel to produce fluorides of uranium and plutonium, and recovering the fluorides using a difference in volatility behavior. The method includes steps of: subjecting a mixture of UO2 and PuO2 with hydrogen fluoride mixed with hydrogen to HF-fluorinate uranium and plutonium into UF4 and PuF3; subjecting UF4 and PuF3 with a fluorine gas to F2-fluorinate uranium and plutonium into UF6 and PuF6; and fractionating UF6 and PuF6 using a difference in phase change of obtained UF6 and PuF6, removing a part of UF6, and volatilizing the remaining UF6 and PuF6 at the same time. By such a reprocessing method, PuF4 hard to undergo a reaction is prevented from being formed as an intermediate fluoride, the material of a reactor is hard to be corroded, and a consumption of expensive fluorine gas is reduced.
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