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use of sodium molybdate in the transesterification of vegetable oils to obtain fatty acid esters by heterogeneous catalysis

机译:钼酸钠在植物油的酯交换反应中通过非均相催化获得脂肪酸酯的应用

摘要

"USE OF SODIUM MOLIBDATE IN TRANSESTERIFICATION OF VEGETABLE OILS TO OBTAIN FATTY ACID ESTERS THROUGH HETEROGENE CATALYSIS". This invention deals with the use of sodium oxosal molybdate (Na ~ 2 ~ MoO ~ 4 ~) as a heterogeneous catalyst for the transesterification of triacylglycerides in oilseed oils such as soybeans to obtain methyl and ethyl fatty acid esters for use. fuel - biodiesel. In addition to facilitating the treatment process of the product obtained, the use of this solid catalyst allows high yields, reduced process costs and less waste generation, considering its reusability. The main advantage in using this catalyst is related to the low temperature employed in the reaction, relatively short reaction times, high degree of recyclability and ease of catalyst synthesis or commercial availability, which favors the implementation of a technically and economically viable industrial process.
机译:“通过异质子催化,将莫来酸钠用于蔬菜油的酯交换,以得到脂肪酸酯”。本发明涉及使用草酸钼酸钠(Na〜2〜MoO〜4〜)作为非均相催化剂,使甘油三酸酯在油籽油(如大豆)中进行酯交换反应,得到甲基和乙基脂肪酸酯。燃料-生物柴油。考虑到其可重复使用性,除了促进所得产物的处理过程外,使用这种固体催化剂还可以提高产量,降低工艺成本并减少废物产生。使用该催化剂的主要优点涉及反应中所用的低温,相对短的反应时间,高度的可循环性以及催化剂合成或商业上的容易获得,这有利于实施技术上和经济上可行的工业方法。

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