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Deproteinized natural rubber latex, method for preparing it, rubber product and uses proteolytic agent for natural rubber latex deproteinization of.

机译:脱胶天然橡胶胶乳,其制备方法,橡胶制品以及使用蛋白水解剂对天然胶乳进行脱蛋白的方法。

摘要

A natural rubber latex deproteinized obtainable by adding a natural rubber latex a protease and two or more surfactants having different coagulation properties to calcium ions (Ca2 +), maturing the natural rubber latex and removing proteins or products of its decomposition, characterized in that one of the at least two surfactants selected from anionic type ester salts ether sulfates higher alkyl and phenyl and anionic type ester salts ether sulfates higher alkyl and has low coagulation properties to Ca 2+ so dispersed stably when the concentration of Ca2 + of an aqueous solution at 25 ° C containing the surfactant is 0.1 mol / l or less, and the other of the at least two surfactants is selected anionic surfactants of the type of carboxylic acids, anionic type sulfate ester salt higher alcohols, anionic type sulfonic acid and anionic-type phosphoric acids and has high coagulation properties to Ca 2+ so coagulated when the Ca 2+ concentration of an aqueous solution at 25 ° C containing the surfactant is 1.0 mol / l or more, and that the weight ratio of the surfactant having low coagulation properties to Ca 2+ to the surfactant having high coagulation properties to Ca 2+ is from 85:15 to 30:70.
机译:通过将天然橡胶胶乳中的蛋白酶和两种或更多种具有不同凝结特性的表面活性剂添加到钙离子(Ca2 +)中,使该天然橡胶胶乳熟化并去除蛋白质或其分解产物,可以得到一种天然橡胶胶乳脱蛋白。至少两种选自阴离子型酯盐醚硫酸盐高级烷基和苯基和阴离子型酯盐醚硫酸盐高级烷基的表面活性剂,对Ca 2+的凝结性能低,因此当水溶液中Ca 2 +的浓度为25时稳定分散包含的表面活性剂的℃为0.1mol / l或更小,并且至少两种表面活性剂中的另一个选自羧酸类,阴离子型硫酸酯盐高级醇,阴离子型磺酸和阴离子型磷酸的阴离子型表面活性剂。酸并且对Ca 2+具有高凝结特性,因此当Ca 2+浓度在25°C的水溶液中含有表面活性剂为1.0mol / l以上,且对Ca 2+的凝固性低的表面活性剂与对Ca 2+的凝固性高的表面活性剂的重量比为85:15〜30:70。

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