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METHOD FOR PREPARING LACTIDE FOR SYNTHESIS OF POLYMER POLY L-LACTIC ACID

机译:制备用于合成聚合物聚L-乳酸的丙交酯的方法

摘要

A method for preparing crude lactide is provided to maximize production yield, to minimize racemization and to obtain the lactide of molten state by optimizing the reaction condition. A method for preparing crude lactide comprises the steps of preparing the poly(lactic acid) having a low molecular weight from lactic acid; and reacting the poly(lactic acid) having a low molecular weight in the presence of a catalyst at a high temperature and at a high pressure. Preferably the molecular weight of the poly(lactic acid) having a low molecular weight is 300-5,000 g/mol; and the catalyst is a metal oxide, a metal halide or a metal carboxylate containing a metal selected from the group consisting of Sn, Zn, Fe and Sb.
机译:提供了一种制备粗丙交酯的方法,其通过最大化反应条件来最大化产率,最小化外消旋化并获得熔融态的丙交酯。一种制备粗丙交酯的方法,包括以下步骤:由乳酸制备具有低分子量的聚乳酸;和使低分子量的聚乳酸在催化剂的存在下在高温高压下反应。低分子量的聚乳酸的分子量优选为300〜5,000g / mol。催化剂是含有选自Sn,Zn,Fe和Sb的金属的金属氧化物,金属卤化物或金属羧酸盐。

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