POLYMER COMPOSITION WITH ELASTOMERIC PROPERTIES WITHIN WIDE TEMPERATURE RANGES AND A METHOD OF PREPARING THE SAME

摘要

FIELD: polymer production.;SUBSTANCE: invention provides elastomeric polymer composition comprising at least polymers and copolymers obtained from substituted and unsubstituted vinylaromatic monomers and from diene monomers and including 15 to 85% copolymer containing (i) at least one block formed by 10 to 5000 mainly syndiotactic structural sequences of monomer units derived from at least one substituted or unsubstituted vinylaromatic monomer and (ii) at least one block formed by 10 to 4000 monomer units derived from at least one diene monomer with predominant 1,4-cis structure, wherein 15-85 wt % of polymer obtained from diene monomers has molecular weight between 6000 and 600000 with content of 1,4-cis monomer units constituting at least 90%, while up to 70% of polymer obtained from substituted and unsubstituted vinylaromatic monomers has molecular weight between 10000 and 500000 and degree of syndiotacticity (expressed through syndiotactic pentads) at least 95%, a part formed by monomer units derived from diene monomer is optionally partially or completely hydrogenised. Method of preparing such elastomeric composition is also described.;EFFECT: extended temperature range for elastomeric performance of composition.;42 cl, 5 tbl, 27 ex