首页> 外国专利> Herbicidal combinations, useful e.g. to combat undesirable plant growth in plants, comprises a 3-phenoxy-1H-pyrazole compound, and a compound containing e.g. inhibitors of protoporphyrinogen oxidase, preferably azafenidin

Herbicidal combinations, useful e.g. to combat undesirable plant growth in plants, comprises a 3-phenoxy-1H-pyrazole compound, and a compound containing e.g. inhibitors of protoporphyrinogen oxidase, preferably azafenidin

机译:除草剂组合,有用的例如为了对抗植物中不希望的植物生长,其包含3-苯氧基-1H-吡唑化合物和含有例如原卟啉原氧化酶抑制剂,最好是阿扎非尼定

摘要

Herbicidal combinations (Q) comprises an effective concentration of at least a 3-phenoxy-1H-pyrazole compound of formula (I) and its salts; and at least a compound (II) comprising e.g. (a) inhibitors of branched amino acid biosynthesis (preferably amidosulfuron), (b) inhibitors of the photosynthetic of electron carrier (preferably atrazine), (c) synthetic auxin (preferably dicamba), (d) inhibitors of fatty acid organic synthesis (preferably cyhalofop) and (e) inhibitors of cell segmentation (preferably alachlor). Herbicidal combinations (Q) comprises an effective concentration of at least a 3-phenoxy-1H-pyrazole compound of formula (I) and its salts; and at least a compound (II) comprising (a) inhibitors of branched amino acid biosynthesis (preferably amidosulfuron, amidosulfuron-sodium, chlorimuron, chlorimuron-ethyl, flazasulfuron, flucarbazone, flucarbazone-sodium, flupyrsulfuron, flupyrsulfuron-methyl-sodium, imazamethabenz, imazamethabenz-methyl, imazamox, imazypyr, iodosulfuron, iodosulfuron-methyl-sodium, mesosulfuron, mesosulfuron-methyl, mesosulfuron-methyl-sodium, metsulfuron, propoxycarbazone, propoxycarbazone-sodium, sulfometuron, sulfometuron-methyl, sulfosulfuron, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, triasulfuron, tribenuron or tribenuron-methyl), (b) inhibitors of the photosynthetic of electron carrier (preferably amicarbazone, atrazine, bromacil, bromacil-sodium, bromoxynil, bromoxynil-heptanoate, bromoxynil-octanoate, bromoxynil-potassium, diuron, ioxynil, ioxynil-octanoate, ioxynil-sodium, isoproturon, metribuzin, simazine, tebuthiuron or terbuthylazine), (c) synthetic auxin (preferably 2,4-dichlorophenoxy acetic acid, 2,4-sodiumdichlorophenoxy acetic acid, clopyralid, clopyralid methyl, dicamba, dicamba methyl, fluroxypyr, fluroxypyr-meptyl, picloram, picloram methyl, quinclorac, quinmerac, triclopyr, triclopyr-ethyl, 2-methyl-4-chlorophenoxyethanoic acid, 2-(4-chloro-2-methyl-phenoxy) propionic acid or dichlorophenoxypropionic acid), (d) inhibitors of fatty acid organic synthesis (preferably clodinafop, clodinafop-propargyl, cyhalofop, cyhalofop-butyl, diclofop, diclofop methyl, fenoxaprop, fenoxaprop-P-ethyl, fluazifop, fluazifop-P-butyl, haloxafop, haloxafop-P-methyl, pinoxaden, quizalofop, quizalofop-P-ethyl, clethodim, sethoxydim or tepraloxydim), (e) inhibitors of cell segmentation (preferably acetochlor, alachlor, fentrazamide, flufenacet, isoxaben, mefenacet, metazachlor, metolachlor, S-metolachlor or thiazopyr), (f) inhibitors of the fatty acid biosynthese-carotinoidbiosynthese (preferably diflufenican, clomazone or picolinafen), (g) inhibitors of hydroxyphenylpyruvate-dioxygenase (preferably isoxaflutole, mesotrione, sulcotrione, pyrasulfotole, tembotrione, tefuryltrione or topramezone), (h) inhibitors of protoporphyrinogen oxidase (preferably azafenidin, butafenacil, carfentrazone, carfentrazone-ethyl, flumiclorac, flumiclorac-pentyl, fomesafen, fomesafen- sodium, lactofen, oxadiargyl or oxyfluorfen), (i) inhibitors of carotenoid biosynthesis (preferably aclonifen, flurtamone or norflurazon), (j) inhibitors of microtubuli construction (preferably oryzalin, pendimethalin or trifluralin), (h) diquat, diquat dibromide, paraquat, paraquat dichloride, naproanilide, pyroxasulfone, glyphosate, glyphosate-trimesium, sulfosate, glufosinate, glufosinate-ammonium or phosphinotricin, (i) inhibitors of cellulose biosynthesis (preferably (S)-2-amino-4-(4-phenyl-1-cyclopropyl-butylamino)-6-(1-fluor-1-methyl-ethyl)-1,3,5-triazine, 2-amino-4-[(1R,2S )-2,6-dimethyl-indan-1-ylamino]-6-[(1RS)-1-fluorethyl]-1,3,5-triazine, 2-amino-4-[(1R,2R)-2,6-dimethyl-indan-1-ylamino]-6-[(1RS)-1-fluoroethyl]-1,3,5-triazine, 2-amino-4-[(1R,2S)-2,6-dimethyl-indan-1-yl-amino]- 6-[(1R)-1-fluoro-ethyl]-1,3,5-triazine, 2-amino-4-[(1R,2R)-2,6-dimethyl-indan-1-ylamino]-6-[(1R)-1-fluoro-ethyl]-1,3,5-triazine or 2-amino-4-[(1R,2S)-2,6-dimethyl-indan-1-yl-amino]-6-[(1S)-1-fluoro-ethyl]-1,3,5-triazine), where the weight ratio of (I) and (II) is 1:800-5000:1. R1H, F, Cl, Br, (1-3C)-alkyl, (2-3C)-alkenyl, (2-3C)-alkynyl, (1-3C)-alkoxy, halo-(1-3C)-alkyl, halo-(1-3C)-alkoxy or CN; R2CF3 or CHF2; R3CH3 or C2H5; A : 1H-pyrazole moiety of formula (a1), pyridine moiety of formula (a2), benzene moiety of formula (a3) or thiophene moiety of formula (a4); R4a : CF3, CHF2, fluoromethyl, trifluoromethoxy or difluoromethoxy; R4b : (1-3C)-alkyl; R5CF3, CHF2, fluoro-methyl, trifluoromethoxy, difluoromethoxy, Cl or CN; R6H, F, Cl, Br or (1-3C)-alkyl; and R7, R8CF3, CHF2, trifluoromethoxy, difluoromethoxy, Cl or CN. [Image] [Image] ACTIVITY : Herbicide. MECHANISM OF ACTION : None given.
机译:除草组合(Q)包含有效浓度的至少一种式(I)的3-苯氧基-1H-吡唑化合物及其盐;至少化合物(II)包括例如(a)支链氨基酸生物合成的抑制剂(最好是氨基磺隆),(b)电子载体的光合作用的抑制剂(最好是阿特拉津),(c)合成生长素(最好是麦草畏),(d)脂肪酸有机合成的抑制剂(最好是(cyhalofop)和(e)细胞分裂抑制剂(最好是草甘膦)。除草组合(Q)包含有效浓度的至少一种式(I)的3-苯氧基-1H-吡唑化合物及其盐;至少一种化合物(II),其包含(a)支链氨基酸生物合成的抑制剂(优选a磺隆,a磺隆钠,氯嘧磺隆,氯嘧磺隆-乙基,黄嘧磺隆,氟卡巴zone,氟咔zone-钠,氟吡嘧磺隆,氟嘧磺隆,氟嘧磺隆,氟嘧磺隆,氟嘧磺隆咪唑甲苯并甲基,咪唑胺,咪唑并,碘磺隆,碘磺隆甲基钠,甲基磺隆,甲基磺隆,甲基磺隆甲基,甲基磺隆,丙氧基卡巴zone,丙氧基脲基甲基,磺胺磺隆,硫磺基,硫磺隆,硫磺隆,硫磺隆噻吩磺隆,甲基噻吩磺隆,三嘧磺隆,苯磺隆或甲基苯磺隆),(b)电子载体光合作用抑制剂(最好是氨基脲,阿特拉津,溴玛西溴铵,溴玛西钠,溴苯甲腈,溴苯甲腈-庚酸溴铵,溴苯甲磺酸-溴铵) ,敌草隆,羟乙腈,辛酸羟乙腈,羟甲磺酸钠,异丙隆,美法津,西玛津,替布丁龙或丁丁嗪),(c)合成助剂n(最好是2,4-二氯苯氧基乙酸,2,4-二氯苯氧基钠,氯吡格雷,氯吡咯烷甲基,麦草畏,麦草畏甲基,氟草烟,氟草烟-甲基,吡咯烷,吡咯烷甲基,喹克洛拉克,喹美拉克,三氯吡喃,三氯乙啶, 2-甲基-4-氯苯氧基乙酸,2-(4-氯-2-甲基苯氧基)丙酸或二氯苯氧基丙酸),(d)脂肪酸有机合成抑制剂(优选clodinafop,clodinafop-炔丙基,cyhalofop,cyhalofop-丁基,双氯芬普,双氯芬普甲基,fenoxaprop,fenoxaprop-P-乙基,fluazifop,fluazifop-P-丁基,haloxafop,haloxafop-P-甲基,pinoxaden,quizalofop,quizalofop-P-乙基,克虫定,扑热息痛或)细胞分裂抑制剂(最好是乙草胺,丙草胺,芬沙酰胺,氟苯乙酰胺,异恶草,美芬乙草,灭草胺,甲草胺,S-间甲草胺或噻唑并吡酯),(f)脂肪酸生物合成-胡萝卜素生物合成抑制剂(最好是双氟苯甲酰氯,氯氟氰菊酯,氯仿, (g)抑制剂羟基苯丙酮酸双加氧酶(最好是异恶唑草酮,甲基磺草酮,磺胺三酮,吡草磺脲,替康三酮,呋喃基三酮或托普拉酮),(h)原卟啉原氧化酶抑制剂(最好是阿扎芬尼丁,丁苯那西芬,氟虫烯,氟虫草,氟虫草,氟虫草,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫草酮,氟虫腈钠,乳粉,草二炔或氧氟芬),(i)类胡萝卜素生物合成抑制剂(优选aclonifen,氟他莫酮或降氟净),(j)微管结构抑制剂(优选Oryzalin,戊二甲戊灵或三氟拉林),(h)敌草快,对草快,百草枯二氯化物,萘丙苯胺,吡ox草砜,草甘膦,草甘膦-三甲铵,亚硫酸盐,草铵膦,草铵膦-铵或膦丝菌素,(i)纤维素生物合成抑制剂(优选(S)-2-氨基-4-(4-苯基-1-环丙基-丁基氨基)-6-(1-氟-1-甲基-乙基)-1,3,5-三嗪,2-氨基-4-[(1R,2S)-2,6-二甲基-茚满-1- ylamino] -6-[((1RS)-1-fluorethyl] -1,3,5-triazine,2-amino-4-[(1R,2R)-2 ,6-二甲基-茚满-1-基氨基] -6-[((1RS)-1-氟乙基] -1,3,5-三嗪,2-氨基-4-[(1R,2S)-2,6-二甲基-茚满-1-基-氨基] -6-[((1R)-1-氟-乙基] -1,3,5-三嗪,2-氨基-4-[(1R,2R)-2,6-二甲基-茚满-1-基氨基] -6-[((1R)-1-氟-乙基] -1,3,5-三嗪或2-氨基-4-[(1R,2S)-2,6-二甲基-茚满-1-基-氨基] -6-[((1S)-1-氟-乙基] -1,3,5-三嗪),其中(I)和(II)的重量比为1:800-5000: 1。 R1> H,F,Cl,Br,(1-3C)-烷基,(2-3C)-烯基,(2-3C)-炔基,(1-3C)-烷氧基,卤代-(1-3C)-烷基,卤代-(1-3C)-烷氧基或CN; R2> CF3或CHF2; R3> CH3或C2H5; A:式(a1)的1H-吡唑部分,式(a2)的吡啶部分,式(a3)的苯部分或式(a4)的噻吩部分; R4a:CF3,CHF2,氟甲基,三氟甲氧基或二氟甲氧基; R4b:(1-3C)-烷基; R5> CF3,CHF2,氟甲基,三氟甲氧基,二氟甲氧基,Cl或CN; R6> H,F,Cl,Br或(1-3C)-烷基; R7>,R8> CF3,CHF2,三氟甲氧基,二氟甲氧基,Cl或CN。 [图像] [图像]活动:除草剂。作用机理:未给出。

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