首页> 外国专利> PROCESS FOR THE PREPARATION OF A TRIBLOC COPOLYMER COMPRISING A SEMI-CRYSTALLINE AND / OR HYDROLYSABLE BLOCK, AN ELASTOMERIC BLOCK AND AN AMORPHOUS BLOCK

PROCESS FOR THE PREPARATION OF A TRIBLOC COPOLYMER COMPRISING A SEMI-CRYSTALLINE AND / OR HYDROLYSABLE BLOCK, AN ELASTOMERIC BLOCK AND AN AMORPHOUS BLOCK

机译:制备包含半结晶和/或可水解嵌段,弹性嵌段和非晶体嵌段的三元共聚物的方法

摘要

The invention relates to a process for preparing a block copolymer comprising a sequence successively comprising a semi-crystalline and / or hydrolysable block, an elastomer block and an amorphous block, comprising the following steps: a) an addition step 1,2 on an ethylenic terminal group of a semi-crystalline and / or hydrolysable polymer of an alkoxyamine which can satisfy the following formula (II): b) an addition step to the medium resulting from step a) d one or more precursor monomers of the elastomer block, whereby a semi-crystalline block-b-elastomeric block diblock copolymer is obtained, c) an addition step to the medium resulting from step b) of one or more precursor monomers of the amorphous block, whereby the semi-crystalline and / or hydrolysable block-triblock copolymer-b-elastomeric-b-block amorphous block is obtained.Application of the copolymers obtained as an amorphous matrix impact modifier.
机译:本发明涉及一种制备嵌段共聚物的方法,该嵌段共聚物包括依次包含半结晶和/或可水解嵌段,弹性体嵌段和无定形嵌段的序列,包括以下步骤:a)在乙烯上的加成步骤1,2。可以满足下式(II)的烷氧基​​胺的半结晶和/或可水解聚合物的端基:b)向步骤a)d所得的介质中添加一种或多种弹性体嵌段的前体单体,得到半结晶嵌段-b-弹性嵌段双嵌段共聚物,c)将步骤b)产生的无定形嵌段的一种或多种前体单体添加到介质中,由此将半结晶和/或可水解嵌段-获得了三嵌段共聚物-b-弹性体-b-嵌段无定形嵌段。获得的共聚物作为无定形基体抗冲改性剂的应用。

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