首页> 外国专利> New crystalline solid zeolite for use as adsorbent or catalyst, shows a characteristic X-ray diffraction pattern and is based on silicon and optionally other elements

New crystalline solid zeolite for use as adsorbent or catalyst, shows a characteristic X-ray diffraction pattern and is based on silicon and optionally other elements

机译:用作吸附剂或催化剂的新型结晶固体沸石,具有特征性的X射线衍射图,基于硅和其他可选元素

摘要

A crystalline solid (IZM-1) with an X-ray diffraction pattern showing very strong lines at 2 theta = 7.60 and 21.22 [deg] , a strong line at 2 theta = 22.96 [deg] and numerous other lines (very weak to average), and with a mixed oxide composition containing tetravalent element(s), optionally trivalent element(s) and optionally alkali and/or alkaline earth metal(s). A crystalline solid (IZM-1) with an X-ray diffraction pattern showing very strong lines at 2 theta = 7.60 and 21.22 [deg] , a strong line at 2 theta = 22.96 [deg] , an average-weak line at 2 theta = 8.78 [deg] , weak lines at 2 theta = 15.24, 21.68 and 23.26 [deg] , and very weak lines at 10.74, 11.43, 12.45, 14.60, 16.93, 17.62, 18.15, 18.73, 19.15, 20.76, 22.58, 24.52, 25.03, 25.44, 25.82, 26.24, 26.56, 29.14, 29.45, 30.79, 31.45, 31.72, 33.04, 33.60, 34.22, 36.28, 37.14 and 38.50 [deg] . The composition of this material, expressed on an anhydrous basis in terms of moles of oxides, is XO 2 : aY 2O 3 : bM 2 / nO, in which X : tetravalent element(s); Y : trivalent element(s); M : alkali or alkaline earth metal; n : valency of M; a : 0-0.02; b : 0-1 . An independent claim is also included for a method for the preparation of IZM-1 by mixing, in an aqueous medium, source(s) of oxide(s) XO 2, possibly source(s) of oxide(s) Y 2O 3, possibly source(s) of alkali and/or alkaline earth metal(s), possibly source(s) of hydroxide ions and at least two different organic species (R) and (S), followed by hydrothermal treatment until the formation of IZM-1, followed by filtration, washing, drying and calcination.
机译:具有X射线衍射图的结晶固体(IZM-1),在2θ= 7.60和21.22°处显示非常强的线,在2θ= 22.96°处显示很强的线,以及其他许多线(非常弱,平均),以及含有四价元素,任选三价元素和任选碱金属和/或碱土金属的混合氧化物组合物。具有X射线衍射图的结晶固体(IZM-1),在2θ= 7.60和21.22°处显示非常强的线,在2θ= 22.96°处显示强线,在2 theta处的平均弱线= 8.78°,在2θ处的弱线= 15.24、21.68和23.26°,并且在10.74、11.43、12.45、14.60、16.93、17.62、18.15、18.73、19.15、20.76、22.58、24.52, 25.03、25.44、25.82、26.24、26.56、29.14、29.45、30.79、31.45、31.72、33.04、33.60、34.22、36.28、37.14和38.50该材料的组成,以氧化物的摩尔数计,基于无水基,为XO 2:aY 2O 3:bM 2 / nO,其中X为四价元素; X为四价元素。 Y:三价元素; M:碱金属或碱土金属; n:M的化合价; a:0-0.02; b:0-1。还包括通过在水性介质中混合一种或多种氧化物XO 2的来源(可能是一种或多种氧化物Y 2O 3的来源)来制备IZM-1的方法的独立权利要求。可能是碱金属和/或碱土金属的来源,可能是氢氧根离子和至少两种不同的有机物(R)和(S),然后进行水热处理直至形成IZM- 1,接着过滤,洗涤,干燥和煅烧。

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