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SOLID LEWIS ACID CATALYST AND MANUFACTURING METHOD OF DIELS-ALDER ADDUCT USING THIS CATALYST

机译:固体路易斯酸催化剂及使用该催化剂的狄尔斯增色剂的制备方法

摘要

PROBLEM TO BE SOLVED: To provide a Lewis acid catalyst which is highly economical in that it can promote Diels-Alder reaction with high yield to monodentate and didentate dienophile compounds, using an applicable equal catalytic amount.;SOLUTION: The solid Lewis acid catalyst (MAO-NTf2) is a chemical compound prepared through a chemical reaction shown by Formula. This chemical compound is composed of a sulfonimide-modified polyaluminoxane in which 13C-NMR of the carbonyl group is made to show a low magnetic field shift and its peak is present between 211.8 to 212.8 ppm when the chemical compound is brought into contact with cyclohexanone.;COPYRIGHT: (C)2009,JPO&INPIT
机译:解决的问题:提供一种经济实用的路易斯酸催化剂,因为它可以使用适当的等量催化量高产率地促进Diels-Alder反应,以单齿或二齿亲二烯化合物的二齿烯。 MAO-NTf 2 )是通过式所示的化学反应制备的化合物。该化合物由磺酰亚胺改性的聚铝氧烷组成,其中羰基的 13 C-NMR表现出较低的磁场位移,当化学反应时,其峰存在于211.8至212.8 ppm之间该化合物与环己酮接触。;版权所有:(C)2009,日本特许厅&INPIT

著录项

  • 公开/公告号JP2009214039A

    专利类型

  • 公开/公告日2009-09-24

    原文格式PDF

  • 申请/专利权人 TOSOH FINECHEM CORP;

    申请/专利号JP20080061129

  • 发明设计人 KACHI EIICHI;HATANAKA YASUO;

    申请日2008-03-11

  • 分类号B01J31/06;C07C45/69;C07C47/445;C07C49/553;C07C67/347;C07C69/753;C07C253/30;C07C255/47;C07C47/42;C07C69/75;C07C49/543;C07B61/00;

  • 国家 JP

  • 入库时间 2022-08-21 19:45:10

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