PROBLEM TO BE SOLVED: To provide a copolymer incorporating a cage structure into the main chain, and to provide a curable resin composition comprising the copolymer.;SOLUTION: The cage structure-containing curable silicone copolymer has a structural unit represented by general formula (1): Y-[Z-(O1/2-R22SiO1/2)a-(R1SiO3/2)n-(O1/2)b]m-Z-Y {wherein R1 and R2 represent each a vinyl group, an alkyl group, a phenyl group, an acryloyl group or a methacryloyl group, an allyl or a group having an oxirane ring; Z represents a divalent group represented by general formula (2); and Y is any of following (3) to (5): (3) [(R4O)R22SiO1/2]a-[R1SiO3/2]n-[O1/2]-, (4) [R4O1/2]b-[R1SiO3/2]n-[O1/2-R22SiO1/2]-, (5) (R4O1/2)-, and (6) (R23SiO1/2)- (wherein, R4 is a hydrogen atom, a methyl group or an ethyl group)}.;COPYRIGHT: (C)2010,JPO&INPIT
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机译:要解决的问题:提供一种在主链中结合有笼结构的共聚物,并提供包含该共聚物的可固化树脂组合物。解决方案:含笼结构的可固化有机硅共聚物具有由通式(1)表示的结构单元):Y- [Z-(O 1/2 Sub> -R 2 Sup> 2 Sub> SiO 1/2 Sub>)< Sub> a Sub>-(R 1 Sup> SiO 3/2 Sub>) n Sub>-(O 1/2 Sub >) b Sub>] m Sub> -ZY {其中R 1 Sup>和R 2 Sup>分别表示乙烯基,烷基基团,苯基,丙烯酰基或甲基丙烯酰基,烯丙基或具有环氧乙烷环的基团; Z表示由通式(2)表示的二价基团;并且Y为以下(3)至(5)中的任何一个:(3)[(R 4 Sup> O)R 2 Sup> 2 Sub> SiO 1/2 Sub>] a Sub>-[R 1 Sup> SiO 3/2 Sub>] n Sub>-[ O 1/2 Sub>]-,(4)[R 4 Sup> O 1/2 Sub>] b Sub>-[R 1 Sup> SiO 3/2 Sub>] n Sub>-[O 1/2 Sub> -R 2 Sup > 2 Sub> SiO 1/2 Sub>]-,(5)(R 4 Sup> O 1/2 Sub>)-, (6)(R 2 Sup> 3 Sub> SiO 1/2 Sub>)-(其中,R 4 Sup>是氢原子,甲基或乙基)} 。;版权所有:(C)2010,日本特许厅&INPIT
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