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Method for producing water-soluble sulfonated organophosphorus compound and organic reaction for carrying out two-phase catalytic reaction

机译:水溶性磺化有机磷化合物的制备方法及进行两相催化反应的有机反应

摘要

Water-soluble sulfonated organophosphorus compounds are purified by at least partially removing contaminating sulfite values therefrom, by decreasing the pH of a solution of such sulfonated organophosphorus compounds to a value of less than or equal to 4, and maintaining the pH of the solution at this value of 4 or less for such period of time as to reduce the weight concentration of sulfite in the solution to less than 100 ppm; the organophosphorus compounds thus purified are well suited for the two-phase cocatalysis of a wide variety of organic reactions.
机译:通过至少部分地从中除去污染的亚硫酸盐值,通过将这种磺化的有机磷化合物的溶液的pH降低到小于或等于4的值并将该溶液的pH维持在此来纯化水溶性的磺化的有机磷化合物。在一段时间内使溶液中亚硫酸盐的重量浓度降低到小于100 ppm的值为4或更小;这样纯化的有机磷化合物非常适合于多种有机反应的两相共催化。

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