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Nitrile copolymer rubber cross-linked product, nitrile copolymer rubber composition, and method for producing the composition
Nitrile copolymer rubber cross-linked product, nitrile copolymer rubber composition, and method for producing the composition
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机译:丁腈共聚物橡胶交联产物,丁腈共聚物橡胶组合物及其制备方法
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摘要
It contains 0.1 to 100 parts by weight of a plasticizer (B) with respect to 100 parts by weight of a nitrile copolymer rubber (A) having 55 to 80% by weight of α, β-ethylenically unsaturated nitrile monomer units. A nitrile copolymer rubber cross-linked product having an embrittlement temperature of -50 to -5 ° C. Preferably, the gasoline permeability coefficient of gasohol having a weight ratio of isooctane / toluene / ethanol of 40/40/20 is 200 g · mm / m 2 · day or less, and preferably, the plasticizer (B) is a specific dicarboxylic acid. It is an ester compound of an acid compound and an ether bond-containing alcohol. According to the present invention, although the content of unsaturated nitrile monomer units is extremely high, the nitrile copolymer has a low embrittlement temperature (excellent cold resistance) and low gasoline permeability resistance (excellent gasoline permeability resistance). A polymer rubber cross-linked product can be provided.
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机译:相对于100重量份的具有55至80重量%的α,β-烯键式不饱和腈单体单元的腈共聚物橡胶(A),其包含0.1至100重量份的增塑剂(B)。脆化温度为-50〜-5℃的丁腈共聚物橡胶交联物。异丁烷/甲苯/乙醇的重量比为40/40/20的汽油的汽油渗透系数优选为200g·mm / m 2·天以下,优选增塑剂(B)为特定的二羧酸。它是酸化合物和含醚键的醇的酯化合物。根据本发明,尽管不饱和腈单体单元的含量非常高,但是腈共聚物具有低的脆化温度(优异的耐寒性)和低的耐汽油渗透性(优异的耐汽油渗透性)。可以提供聚合物橡胶交联产物。
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