a chlorin dimer represented by Chemical Formula (I):; ;wherein A is CnH2n (n is an integer of 0 or more); and R1, R2, R3R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, and R16 are the same or different, and are each a hydrogen atom, a saturated hydrocarbon group, an aryl group that may be substituted, a heteroaryl group that may be substituted, or an aralkyl group that may be substituted; ora metal chlorin dimer represented by Chemical Formula (II):; ;wherein M2+ is a divalent metal ion; and A, R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, and R16 are the same as defined above. Each of the chlorin dimer and the metal chlorin dimer exhibits at least two peaks in an ultraviolet to visible region of a circular dichroism spectrum and a UV-visible absorption spectrum thereof."/> STANDARD SAMPLE FOR TEST AND /OR CALIBRATION OF CIRCULAR DICHROISM DISPERSION METER AND UV-VISIBLE SPECTROPHOTOMETER
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STANDARD SAMPLE FOR TEST AND /OR CALIBRATION OF CIRCULAR DICHROISM DISPERSION METER AND UV-VISIBLE SPECTROPHOTOMETER

机译:圆二色谱色散计和紫外可见分光光度计的测试和/或校准标准样品

摘要

A principal object of the present invention is to provide a standard sample that allows accurate testing and calibration of a circular dichroism spectrometer, and which can also be applied to testing and calibration of a UV-visible spectrophotometer. The present invention relates to a standard sample for use in testing and/or calibrating a circular dichroism spectrometer and a UV-visible spectrophotometer, which standard sample comprising:a chlorin dimer represented by Chemical Formula (I):; ;wherein A is CnH2n (n is an integer of 0 or more); and R1, R2, R3R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, and R16 are the same or different, and are each a hydrogen atom, a saturated hydrocarbon group, an aryl group that may be substituted, a heteroaryl group that may be substituted, or an aralkyl group that may be substituted; ora metal chlorin dimer represented by Chemical Formula (II):; ;wherein M2+ is a divalent metal ion; and A, R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, and R16 are the same as defined above. Each of the chlorin dimer and the metal chlorin dimer exhibits at least two peaks in an ultraviolet to visible region of a circular dichroism spectrum and a UV-visible absorption spectrum thereof.
机译:本发明的主要目的是提供一种标准样品,其可以对圆形二向色光谱仪进行精确的测试和校准,并且还可以应用于紫外线可见分光光度计的测试和校准。本发明涉及用于测试和/或校准圆二色性光谱仪和紫外可见分光光度计的标准样品,该标准样品包括: 由化学式(I)表示的二氢卟酚二聚体: ; ;其中A为C n H 2n (n为0或更大的整数);和R 1 ,R 2 ,R 3 R 4 ,R 5 , R 6 ,R 7 ,R 8 ,R 9 ,R 10 , R 11 ,R 12 ,R 13 ,R 14 ,R 15 ,和R 16 相同或不同,分别为氢原子,饱和烃基,可被取代的芳基,可被取代的杂芳基或可被取代的芳烷基。被取代;要么 由化学式(II)表示的金属二氢卟吩二聚体: ; ;其中M 2 + 为二价金属离子;和A,R 1 ,R 2 ,R 3 ,R 4 ,R 5 ,R 6 ,R 7 ,R 8 ,R 9 ,R 10 ,R 11 ,R 12 ,R 13 ,R 14 ,R 15 和R 16 与上面定义的相同。二氢卟酚二聚体和金属二氢卟酚二聚体在圆形二色性光谱的紫外至可见光区域及其紫外可见吸收光谱中均显示至少两个峰。

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