Azociclicas amides fungicides, which include Fungicide compositions and their use in a method for controlling plant Diseases caused by fungal pathogens of the class of oomycetes.

摘要

It also reveals ingredients containing formula compound (1) and methods of controlling plant etiology, including the effective use of a compound or current ingredient. Item 1: a compound whose characteristics are selected from a formula compound (1),an N-oxide and its salts, wherein R1 is an optionally substituted 5- or 6-membered phenyl, naphthalenyl or heteroaromatic ring; A is CHR15 or R16; R15 is H, halogen, cyano, hydroxy, -CHO, C1-4 alkyl, C2-4 alkenyl, C2-4 alkynyl, C1-4 haloalkyl, C2-4 haloalkenyl, C2-4 alkoxyalkyl, C2 alkylthioalkyl -4, C2-4alkylsulfinylalkyl, C2-4alkylsulfonylalkyl, C2-4alkylcarbonyl, C2-4alkylcarbonyl, C2-5alkoxycarbonyl, C3-5alkoxycarbonylalkyl, C3-5alkylaminocarbonyl, C1-4alkoxycarboxy, C1-4alkoxycarbonyl -4, C1-C4alkylthio, C1-4 haloalkylthio, C1-4alkylsulfinyl, C1-4 haloalkylsulfinyl,alquilsulfonilo C1-4 o haloalquilsulfonilo C1-4 R16 es H alquilo C1-4 alquenilo C2-4 alquinilo C2-4 haloalquilo C1-4 haloalquenilo C2-4 haloalquinilo C2-4 alcoxialquilo C2-4 alquiltioalquilo C2-4 alquilsulfinilalquilo C2-4 alquilsulfonilalquilo C2 Each R2 is a separate C1-4 tar, alquenilo C1-4, C1-4 halotar, alcoxi C1-4, halogeno, Ciano or hidroxi; O 2r2 is mixed as C1-4 or c2-4 tar to form a double ring system with bridge or double ring combination;O 2r2 is combined with adjacent carbon atoms and has a double link. One or three alternatives selected from C1-4 tar, C1-4 halogenated tar, Alcoy C1-4, haloxy C1-4, haloxy C1-4, halogeno, hydroxi, amino, Ciano and Niro are used instead of un-ch = ch-ch; G is a 5-member heteroaromatic ring, or a 5-member saturated or partially saturated alternative heterocyclic ring; J is a 5, 6 or 7-member ring, a 8-to-11-member double ring system, or a 7-to-11-member spiral ring system,Each ring or ring system has members selected from carbon, 1 to 4 heteroatoms selected from 2 or 2 to 2 ml to 4 ml, and 1 to 3 ring members selected from group C (= O),C (=s),Yes, that is.S (O) 2 and SiR17R18, each ring or ring system optionally substituted with between 1 and 5 substituents independently selected from R5; each R5 is independently H, halogen, cyano, hydroxy, amino, nitro, -CHO, -C (= O) OH, -C (= O) NH2, -NR25R26, C1-6 alkyl, C2-6 alkenyl, C2-6 alkynyl, C1-6 haloalkyl, C2-6 haloalkenyl, C2-6 haloalkynyl, C3-8 cycloalkyl, C3-8 halocycloalkyl, C4-10 cycloalkylalkyl, C6-14 cycloalkylcycloalkyl, C4-10 haloalkylcycloalkyl, C5-10 alkylcycloalkylalkyl, C3-8 cycloalkenyl, C3-8 halocycloalkenyl, C2-6 alkoxyalkyl, C4-10 cycloalkoxyalkyl, C2-6 alkoxyalkoxyalkyl,C2-6alkylsulfinylalkyl, C2-6alkylsulfonylalkyl, C2-6alkylaminoalkyl, C3-8 dialkylaminoalkyl, C4-10 cycloalkylaminoalkyl, C2-6alkylcarbonyl, C2-6cycloalkylcarbonyl, C2-cycloalkylcarbonyl C4-8 cycloalkoxycarbonyl, C5-10 cycloalkylalkylcarbonyl, C2-6 alkylaminocarbonyl, C3-8 dialkylaminocarbonyl, C4-8 cycloalkylaminocarbonyl, C6-6-hydroxyalkyl, C1-6-alkoxy, C1-6-cycloalkoxy, C3-8 halocycloalkoxy, C4-10 cycloalkylalkoxy, C2-6 alkenyloxy, C2-6 haloalkenyloxy, C2-6 alkynyloxy, C2-6 alkoxyalkoxy, C2-6 alkylcarbonyloxy,C2-6 haloalkylcarbonyloxy, C4-8 cycloalkylcarbonyloxy, C3-6 alkylcarbonylalkyl, C1-6 alkylthio, C1-6 haloalkylthio, C1-6 cycloalkylthio, C1-6alkylsulfinyl, C1-6alkylsulfonyl, C1-6alkylsulfonyl C3-8 cycloalkylsulfonyl, C3-10 trialkylsilyl, C1-6 alkylsulfonylamino, C1-6 haloalkylsulfonylamino or Z2Q; R25 is H, C 1-6 alkyl, C 1-6 haloalkyl, C 3-8 cycloalkyl, C 2-6 alkylcarbonyl, C 2-6 haloalkylcarbonyl, C 2-6 alkoxycarbonyl or C 2-6 haloalkoxycarbonyl; R26 is C1-6 alkyl, C1-6 haloalkyl, C3-8 cycloalkyl, C2-6 alkylcarbonyl, C2-6 haloalkylcarbonyl, C2-6 alkoxycarbonyl, C2-6 haloalkoxycarbonyl or -Z4Q;Each R17 and R18 is an independent C1-5 tar of C1-5, c2-5 alquenilo c2-5, c2-5, c3-5, C3-6 halocycloethane, c4-10, C4-7, C5-7, C1-5 or halogenated alcox C1-5; each q is an independent aromatic hydrocarbon based on benzene, Nile, heterochromatic and aromatic hydrocarbon. 5 to 6 members or 8 to 11 members of the odor double ring system,One to five substitutes selected from R7 and R12 in the cyclic carbon atom and cyclic nitrogen atom replace each substitute, or each q is an independent three to seven member aromatic free carbon ring, five, six or seven member aromatic free heterocyclic ring or one member aromatic free carbon ring. A fragrance free double ring system consisting of 8 to 11 members,Each ring includes optional ring members (= O) selected from group C,C (=s),Yes, that is.Each R7 is C1-6, alquenilo c2-6, c12-6, c12-6, C3-6, cyclo-6, cyclo-cyclo-c4-10, acrylonitrile-lquil, acrylonitrile-10, propylene glycol. 1-4, 1-4, 1-4, 1-4, 1-4, 1-4, 1 1-4, 1-4, 1-4, 1-4, 1 1 1-4, C1-4C2-4, C3-6 Cyclamine, c2-4, C1-4 oxygen tar, c2-4 asphalt, c2-4, oxycarbide c2-6, carbohydrate c2-6, carbohydrate c2-6, carbonate c2-6, rental c2-6, carbonate C3-8 or trial quilsililo C3-6; R5 and R7, together with the atoms combined with R5 and R7, form a ring of 5 to 7 substitute members, which contains 2 to 7 carbon atoms as members of the ring, and can optionally be between 1 to 3 heteromorphic atoms selected from 1 or 1. No more than 1s and no more than 1n, including 1 to 3 members of the ring selected from group C.C (=s),Yes, that is.S (o) 2 and sir17r18; R12 is h, c1-3 tar, c1-3 tar, alcox c1-3 or alcoxicarbon c1-3; each Z1 and Z2 is an independent direct link, O, C (= O),S (o) m, chr20 or N21; each Z4 is a separate o, C (= O),S (o) m or ch20; each R20 is an independent h, C1-4 tar or C1-4 halide; each R21 is an independent h, C1-6 tar, C1-6 halide, C1-6 epoxy C3-8, c2-6, c2-6 halocarbon, c2-6 or c2-6 halocarbon; each m is an independent 0, 1 or 2; N, 0 or 2; But (a) if R1 is unreplaced, X is x1, and the ring containing x is saturated, G is an unreplaced thiazole ring, connected at the position of 2 and X and at the position of 4 and Z1 in Formula 1, a is CH15, R15 is h,J is a heteroxazol ring, connected to position 4 and Z1, replaced at position 5 and methyl, replaced at position 3, so Z1 is O, C (= O),S (o) m, ch20 or N21, y (b) when a is nr16, X is X1 or X2, Z1 is a direct link,J is phenyl, so J is replaced by at least one R5 different from h, F, CI, CN, OCH3, CF3, and CH3. ILO Convention No. 17: a compound selected from 1b, N-oxidation and its salts, wherein each r4a1 and r4a2 is c1-3, alquenilo C2-3, tar C2-3, cycloacrylonitrile, c1-3, haloalquenilo C2-3, halogenio C2-3, halogenio C2-3, halopentane, halogenated, cyanogen, nitrate, alcox C1-2 and other independent forms, C1-2, C1-2, C1-2, C1-2, halogiodio C1-2, alcoxicologio C2-3, c12-3, alcoxicaronio C2-3, lease minocarbonio C2-3, or diaklaminocarbonio C3-4;and Z3 is CN or C (= S) NH2. Claim 20: A compound characterized in that it is selected from a compound of formula 1C, an N-oxide and a salt thereof, wherein M is C1-3 alkyl, C1-3 haloalkyl, hydroxy, C1-4 alkoxy, C1- haloalkoxy 2, C1-4 alkylamino, C2-8 dialkylamino, 1-piperidinyl, 1-pyrrolidinyl or 4-morpholinyl; and J1 is like in formulas (3).