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ENVIRONMENTALLY BENIGN AND SIMPLIFIED METHOD FOR PREPARATION OF AROMATIC DICARBOXYLIC ACID

机译:制备双羧酸的环境友好性及其简化方法。

摘要

Disclosed is an environmentally benign and simplified method for preparing aromatic dicarboxylic acid. In the disclosed method, a mixed solvent composed of aromatic mono- carboxylic acid and water, instead of conventionally used low molecular weight carboxylic acid such as acetic acid, is used as a reaction solvent for an oxidation process; manganese and a small amount of transition metal element are used as catalysts; and carbon dioxide is used as a reaction stabilizer. Accordingly, it is possible to improve the yield and selectivity of the aromatic dicarboxylic acid.
机译:公开了一种环境友好且简化的制备芳族二羧酸的方法。在公开的方法中,由芳族一元羧酸和水组成的混合溶剂代替了常规使用的低分子量羧酸如乙酸,被用作氧化过程的反应溶剂。锰和少量过渡金属元素用作催化剂;二氧化碳用作反应稳定剂。因此,可以提高芳族二羧酸的收率和选择性。

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