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A PROCESS FOR THE PREPARATION OF 3-HYDROXY-γ-BUTYROLACTONE

机译:3-羟基-γ-丁内酯的制备方法

摘要

The present invention relates to a process for the preparation of 3-hydroxy-y-butyrolactone (V) which comprises: (a) reacting a mixture of a 3-leaving group substituted precursor compound selected from the group consisting of a pentose, a furanose and a pentanal of the formula, as given in the description, with a solvent containing a peroxide in the presence of a base to produce 3,4-dihydroxybutanoic acid (I) and a protonated leaving group; and (b) treating the 3,4-dihydroxybutanoic acid (I) with an acid and heat to form the 3-hydroxy-y-butyrolactone (V).
机译:本发明涉及3-羟基-γ-丁内酯(V)的制备方法,该方法包括:(a)使选自戊糖,呋喃糖的3-离开基团的取代的前体化合物的混合物反应。说明书中所述的式的戊醛,在碱的存在下用含有过氧化物的溶剂制得3,4-二羟基丁酸(I)和质子化的离去基团; (b)用酸和加热处理3,4-二羟基丁酸(I)以形成3-羟基-γ-丁内酯(V)。

著录项

  • 公开/公告号IN230050B

    专利类型

  • 公开/公告日2009-03-27

    原文格式PDF

  • 申请/专利权人

    申请/专利号IN2477/CHENP/2005

  • 发明设计人 HOLLINGSWORTH RAWLE I;

    申请日2005-09-30

  • 分类号C07C51/00;

  • 国家 IN

  • 入库时间 2022-08-21 19:26:43

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