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Modified Amine ALDEHYDE resins and their applications in separation processes

机译:改性胺醛树脂及其在分离过程中的应用

摘要

Refers to modified Resins for use in separation processes, and especially the selective separation of solid and / or Ionic species such as metal cations from aqueous media.The modified Resins comprise a base Resin which is modified by a coupling Agent that is highly Selective for the Union with Solid Pollutants and especially siliceous materials such as Sand or Clay.In addition, a method is described that includes: (a) providing an element containing one or more impurities; b) contacting Said element with a Resin Amine aldehyde comprising a Silane coupling agent; and c) During or after the step (b) separating the impurity Complex Resin The Purified material, so that the Resin is mixed Reagents of formaldehyde, ureaTriethanolamine and optionally Ammonia at an Alkaline pH, the mixture is heated to a high temperature, and adding acid to reduce the pH to a range of 4.9 to 5.2 and add urea to the molar ratio of formaldehyde to urea in the range 1.5 to 2.5: 1: 1 and REACT during a certain time PO sufficient to reduce the free formaldehyde to less than 2%
机译:指用于分离过程中的改性树脂,尤其是从水性介质中选择性分离固体和/或离子物种(如金属阳离子)的方法。改性树脂包含一种基础树脂,该树脂通过高度选择性的偶联剂进行改性此外,还描述了一种方法,该方法包括:(a)提供一种含有一种或多种杂质的元素; b)使所述元件与包含硅烷偶联剂的树脂胺醛接触; c)在步骤(b)中分离杂质复合树脂的过程中或之后,将纯化的材料混合以在碱性pH下混合甲醛,脲三乙醇胺和任选的氨的试剂,将混合物加热至高温,并加入酸以将pH值降低至4.9至5.2,并在甲醛与尿素的摩尔比为1.5至2.5:1:1的范围内添加尿素,并在一定时间内进行REACT,足以将游离甲醛减少至小于2 %

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