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New type odor molecule with Sandalwood, process for their preparation and use thereof as odorant.

机译:具有檀香的新型气味分子,其制备方法及其用作气味剂的用途。

摘要

The present invention comprises the preparation of a novel odorant (1), preparation thereof from (1R) - (-) - nopol (2) and use thereof as a sandalwood type ingredient in the production of perfumery compositions. Obtaining (1) from (2) is achieved in five steps with a global return of 25%, by means of the following transformations: (a) catalytic hydrogenation, (b) oxidation to hydroxile group aldehyde (c) aldol condensation of the resulting aldehyde with butanone, (d) deconjugation and a-methylation of the aldol condensation product, and (e) reduction of the carbonyl group
机译:本发明包括新型气味剂(1)的制备,其从(1R)-(-)-nopol(2)的制备以及其作为檀香型成分在香料组合物生产中的用途。从(2)中获得(1)的过程可通过以下五个步骤分五个步骤完成,总体回报率为25%:(a)催化加氢,(b)氧化为羟基醛基(c)醛醇缩合生成的醛与丁酮,(d)醛醇缩合产物的脱共轭和α-甲基化,以及(e)羰基的还原

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