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Base coating composition for decorated moldings, top clear coating composition for decorated moldings, and decorated moldings

机译:装饰线条的基础涂料组合物,装饰线条的顶部透明涂料组合物和装饰线条

摘要

It is an object of the present invention to provide a base coating composition for decorated moldings containing silver plating layer and a top clear coating composition for decorated moldings containing silver plating layer, and decorated moldings obtainable by using these compositions; the compositions and moldings are to be excellent in silver deposition tendency, basecoat film smoothness, adhesion and/or film appearance. ??A base coating composition for decorated moldings containing silver plating layer comprising a main composition for base coating comprising an acrylic polyol (A1), an organic-modified polydimethylsiloxane (A2) and an epoxysilane (A3) represented by the chemical scheme (1): CHEM in the scheme, R1 represents a methyl, methoxy or ethoxy group and R2 and R3 are the same or different and each represents a methoxy or ethoxy group, and a curing agent for base coating comprising a polyisocyanate, wherein the base coating composition for decorated moldings is a two-package curing type urethane coating composition, in the main composition for base coating, the (A2)/(A1) ratio is 0.02/100 to 0.20/100 on the solid weight basis and the (A3)/(A1) ratio is 1.5/100 to 5.5/100 on the solid weight basis, and the equivalent ratio between the NCO groups in the curing agent for base coating and the OH groups in the acrylic polyol (A1), namely the NCO/OH equivalent ratio, is 1.5 to 3.0.
机译:本发明的一个目的是提供一种包含银镀层的用于装饰模制品的底涂料组合物和一种包含银镀层的用于装饰模制品的顶部透明涂料组合物,以及通过使用这些组合物可获得的装饰模制品。该组合物和模制品应具有优异的银沉积趋势,底漆膜的光滑度,粘合性和/或膜外观。包含银镀层的装饰模制品用基础涂料组合物,其包含用于基础涂料的主要组合物,所述主要组合物包含由化学方案表示的丙烯酸多元醇(A1),有机改性的聚二甲基硅氧烷(A2)和环氧硅烷(A3)。 1):方案中的,R 1代表甲基,甲氧基或乙氧基,R 2和R 3相同或不同,分别代表甲氧基或乙氧基,和固化剂用于包含多异氰酸酯的基础涂料的涂料,其中用于装饰模制品的基础涂料组合物是两包装固化型聚氨酯涂料组合物,在用于基础涂料的主要组合物中,(A2)/(A1)比为0.02 / 100至0.20 /固体成分为100时,(A3)/(A1)之比为1.5 / 100〜5.5 / 100,基础涂料用固化剂中的NCO基与OH基中的OH当量比。丙烯酸多元醇(A1)的NCO / OH当量比为1.5〜3.0。

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