首页> 外国专利> FABRICATION OF TITANIA/POLYMER CORE-SHELL NANOPARTICLE AND APPLICATION FOR TRANSPARENT THIN FILM POLYMER NANOCOMPOSITE WITH HIGH REFRACTIVE INDEX

FABRICATION OF TITANIA/POLYMER CORE-SHELL NANOPARTICLE AND APPLICATION FOR TRANSPARENT THIN FILM POLYMER NANOCOMPOSITE WITH HIGH REFRACTIVE INDEX

机译:钛/聚合物核壳纳米粒子的制备及其在高折射率下透明薄膜聚合物纳米复合材料的应用

摘要

The present invention is titania / polymer core - relates to the manufacture of the cell nanoparticles, titanium oxide nanoparticles the in-core (core) component, and dispersed in an aqueous solution after a predetermined amount of titanium oxide nanoparticles, by using a silane coupling agent to the dispersed titanium oxide nanoparticles after modifying the surface hydrophobic, by introducing additional monomer and initiator core by coating the surface of the titanium dioxide nanoparticles to the polymer formed in the cell (shell) component using a seed polymerization takes place but not limited to the surface of the titanium oxide nanoparticles at an appropriate temperature and time - method for producing a cell nanoparticles provides. ; According to the present invention, a simple and inexpensive process by using the titania / polymer core - has the advantage that can be easily produced in a cell nanoparticles. Furthermore, the core, which may be prepared in the present invention as well as cells nanoparticles not be bound by the size and shape of the core component, the type of the polymer cell, it is possible without restrictions on thickness prepared. Seen from the process point of view, this reaction is conducted in a non-volatile solution, has the advantage of mass production and the recovery of the nanocomposite that is easy. In addition, the titanium oxide / polymer core-shell nanoparticles with a polymer by mixing the titanium oxide / polymer core-time cell hayeoteul nanomaterial manufacturing a polymer thin film containing the composite material, the transparency is not reduced compared to the conventional polymer film, the refractive index proposes the improved characteristics.
机译:本发明是二氧化钛/聚合物核-涉及细胞纳米粒子的制造,二氧化钛纳米粒子为核内(核)成分,并通过硅烷偶联在预定量的二氧化钛纳米粒子后分散于水溶液中通过种子聚合将二氧化钛纳米颗粒的表面涂覆到细胞(壳)成分中形成的聚合物上,引入额外的单体和引发剂核,从而对表面疏水性进行改性后,向分散的二氧化钛纳米颗粒中加入分散剂,但不限于此。在合适的温度和时间下,钛氧化物纳米颗粒的表面-提供了一种生产细胞纳米颗粒的方法。 ;根据本发明,通过使用二氧化钛/聚合物核的简单且廉价的方法-具有可以容易地在细胞纳米颗粒中生产的优点。此外,可以在本发明中制备的芯以及不受芯组分的尺寸和形状,聚合物电池的类型约束的细胞纳米颗粒,可以不受制得的厚度的限制。从工艺角度看,该反应在非挥发性溶液中进行,具有批量生产和容易回收纳米复合材料的优点。另外,通过将氧化钛/聚合物核-壳纳米粒子与聚合物混合,将氧化钛/聚合物核-壳纳米粒子与聚合物混合,制造出包含复合材料的聚合物薄膜,与传统的聚合物膜相比,透明性不会降低,折射率具有改善的特性。

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