METHOD OF OBTAINING COMPLEXES OF TRICRESYL-, TRI(1,3-DICHLOROPROPYL)- AND TRI(2-ETHYLHEXYL)PHOSPHATES WITH Sn AND Ti CHLORIDES

摘要

FIELD: chemistry.;SUBSTANCE: present invention pertains to the method of obtaining complexes of tricresyl-, tri(1,3-dichloropropyl) and tri(2-ethylhexyl)phosphates with Sn and Ti chlorides, with general formula 2(RO)₃P=O•"Э"Cl₄, where R=-C₄H₆CH₃, -CH(Cl)CH₂CH₂(Cl) or -CH₂CH(C₂H₅)(CH₂)₃CH₃, "Э" = Sn, Ti, and can be used in organic synthesis. The method is characterised by that, it involves reaction of tricresyl-, tri(1,3-dichloropropyl)- or tri(2-ethylhexyl)phosphate with Sn and Ti tetrachlorides at room temperature and molar ratio of phosphate : tetrachloride 2:1.;EFFECT: design of an effective method of obtaining complexes.;1 cl, 6 ex, 2 tbl