首页> 外国专利> Washing- or cleaning agent, useful e.g. for cleaning colored textile fabrics, comprises color transfer inhibitor in the form of e.g. polycarbonate compound comprising carbonyl structural element or its acid compound and/or their salts

Washing- or cleaning agent, useful e.g. for cleaning colored textile fabrics, comprises color transfer inhibitor in the form of e.g. polycarbonate compound comprising carbonyl structural element or its acid compound and/or their salts

机译:洗涤或清洁剂,例如用于清洁有色纺织物的织物,包括颜色转移抑制剂,例如包含羰基结构元素的聚碳酸酯化合物或其酸化合物和/或其盐

摘要

Washing- or cleaning agent (A) comprises a color transfer inhibitor in the form of a polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compounds comprising at least a carbonyl structural element (I) or its acid addition compound and/or their salts. Washing- or cleaning agent (A) comprises a color transfer inhibitor in the form of a polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compounds comprising at least a carbonyl structural element of formula (-Y 1-A-(C=O)-A-) (I) or its acid addition compound and/or their salts. Either A : S, O or NR 1; Y 1bivalent to polyvalent, preferably tetravalent, optionally saturated or aromatic hydrocarbon with up to 1000C containing one or more NR 2, (N +R 2R 3) (both preferred), O, (CO), NH, 2-1000 polyorganosiloxane unit with silicon atom (optionally substituted), preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); or Y 1A : nitrogen containing heterocyclic ring; R 1H, optionally saturated or aromatic hydrocarbon with up to 40C, containing one or more O, (CO), NH, NR 2, preferably oligoethoxy and/or oligopropoxy, where its oligomerization degree is preferably 2-60 or oligoethylene imine, where its oligomerization degree is preferably 10-150000; R 2optionally saturated, aromatic hydrocarbon with up to 40C containing one or more O, (CO), NH, preferably oligoethoxy and/or oligopropoxy, where its oligomerization degree is preferably 2-60 or oligoethylene imine, where its oligomerization degree is preferably 10-150000; and R 3optionally saturated, aromatic hydrocarbon with up to 100C containing one or more O, (CO), NH, a bivalent residue, which form cyclic structures within the Y 1, preferably oligoethoxy and/or oligopropoxy, where its oligomerization degree is preferably 2-60 or oligoethylene imine, where its oligomerization degree is preferably 10-15,0000. Provided that: in formula (I) A, Y 1, R 1, R 2, R 3 are not same when at least one of the residues of Y 1 is polyorganosiloxane unit with 2-1000 silicon atom. An independent claim is included for (A) comprising the color transfer inhibitor in the form of (1,3)dioxolan-2-one compound of formula (IV) or (1,3)-diazepan-2-one compound of formula (V) and/or polymer, where the polymer is obtained by the reaction of a polymer substrate that modifies the functional groups of hydroxy-, primary and secondary amino- group with (IV) or (V). R : 1-12C-alky; X : CO-CH=CH 2, CO-C(CH 3)=CH 2, CO-O-aryl, 2-6C-alkylene-SO 2-CH=CH 2 or CO-NH-R 1; R 11-30C-alkyl, 1-30C-haloalkyl, 1-30C-hydroxyalkyl, 1-6C-alkyloxy-1-30C-alkyl, 1-6C-alkylcarbonyloxy-1-30C-alkyl, amino-1-30C-alkyl, mono- or di(1-6C-alkyl)amino-1-30C-alkyl, ammonio-1-30C-alkyl, polyoxyalkylene-1-30C-alkyl, polysiloxanyl-1-30C-alkyl, (meth)acryloyloxy-1-30C-alkyl, sulfono-1-30C-alkyl, phosphono-1-30C-alkyl, di(1-6C-alkyl)-phosphono-1-30C-alkyl, phosphonato-1-30C-alkyl, di(1-6C-alkyl) phosphonato-1-30Calkyl or a saccharide; and k : greater than 0. Provided that: in formula (I) when k is 1, X has the above variable or when k is greater than 1 X is: (i) polyamine bounded with ((CO)-NH) or (ii) polymer skeleton bounded with (CO)-, NH-2-6C-alkylene-O(CO)- or (CO)-O-2-6C-alkylene-O(CO)- or (iii) polymer skeleton bounded with (CO)-polysiloxanyl-1-30C-alkyl-groups. [Image] .
机译:洗涤剂或清洁剂(A)包含呈聚碳酸酯,聚氨酯和/或聚脲-聚有机硅氧烷化合物形式的变色抑制剂,该化合物至少包含羰基结构元素(I)或其酸加成化合物和/或其盐。洗涤剂或清洁剂(A)包含呈色聚抑制剂,呈聚碳酸酯-,聚氨酯和/或聚脲-聚有机硅氧烷化合物的形式,该化合物至少包含式(-Y 1> -A-(C = O)-A-)(I)或其酸加成化合物和/或其盐。 A:S,O或NR 1>; Y 1>二价至多价,优选为四价,任选地饱和或芳族烃,最高至1000C,其包含一个或多个NR 2>,(N +> R 2> R 3>)(均优选),O,(CO),NH ;具有硅原子的2-1000聚有机硅氧烷单元(任选地被取代),优选为低聚乙氧基和/或低聚丙氧基(其中其低聚度优选为2-60)或低聚乙烯亚胺(其中其低聚度优选为10-150000);或Y 1> A:含氮杂环;或R 1> H,至多40℃的任选饱和或芳族烃,其包含一种或多种O,(CO),NH,NR 2>,优选低聚乙氧基和/或低聚丙氧基,其中其低聚度优选为2-60或低聚亚乙基亚胺,其低聚度优选为10-150000; R 2>至多40℃的任选饱和的芳族烃,其包含一种或多种O,(CO),NH,优选低聚乙氧基和/或低聚丙氧基,其低聚度优选为2-60,或低聚亚乙基亚胺,其中其低聚度优选为10-150000;和R 3>至多100℃的任选饱和的芳族烃,其包含一个或多个O,(CO),NH,二价残基,其在Y 1内形成环状结构,优选低聚乙氧基和/或低聚丙氧基,其中其低聚度优选为2-60或低聚亚乙基亚胺,其中其低聚度优选为10-15,0000。假设:在式(I)中,当Y 1>的至少一个残基为具有2-1000个硅原子的聚有机硅氧烷单元时,Y 1>,R 1>,R 2>,R 3>不相同。对于(A)包括独立权利要求,其包含形式为(1,3)的式(IV)二氧戊环-2-酮化合物或式(1,3)-二氮杂-2-酮化合物形式的颜色转移抑制剂V)和/或聚合物,其中该聚合物是通过使(IV)或(V)修饰羟基,伯氨基和仲氨基的官能团的聚合物底物反应而获得的。 R:1-12C-烷基; X:CO-CH = CH 2,CO-C(CH 3)= CH 2,CO-O-芳基,2-6C-亚烷基-SO 2 -CH = CH 2或CO-NH-R 1; R 1> 1-30C-烷基,1-30C-卤代烷基,1-30C-羟烷基,1-6C-烷氧基-1-30C-烷基,1-6C-烷基羰基氧基-1-30C-烷基,氨基-1-30C -烷基,单或二(1-6C-烷基)氨基-1-30C-烷基,铵基-1-30C-烷基,聚氧化烯-1-30C-烷基,聚硅氧烷基-1-30C-烷基,(甲基)丙烯酰氧基-1-30C-烷基,磺基-1-30C-烷基,膦酰基-1-30C-烷基,二(1-6C-烷基)-膦酰基-1-30C-烷基,膦酰基-1-30C-烷基,二( 1-6C-烷基)膦酰基-1-30C烷基或糖;并且k:大于0。假设:在式(I)中,当k为1时,X具有上述变量,或者当k大于1时,X为:(i)与((CO)-NH)或( ii)与(CO)-,NH-2-6C-亚烷基-O(CO)-或(CO)-O-2-6C-亚烷基-O(CO)-结合的聚合物骨架或(iii)与(CO)-聚硅氧烷基-1-30C-烷基。 [图片] 。

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