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recovery of precious metals from aqueous verfahrensstru00f6men in the synthesis of glyphosate using absorptionsmedien as ion-exchange resins

机译:吸收剂作为离子交换树脂在草甘膦合成中从ververhrensstr u00f6men中回收贵金属

摘要

Claim 1: a process for recovering noble metal from a process Stream comprising an aqueous Solubilized noble metal and is generated in a process to make a product N - (PHOSPHONOMETHYL) glycine by oxidation catalyzed by a noble metal substrate acid n - (PHOSPHONOMETHYL) i Minodiacu00e9tico,The recovery process is characterised in that it comprises: contacting at least a portion of the aqueous process flow generated in the process to make a product N - (PHOSPHONOMETHYL) glycine by oxidation catalyzed by a noble metal substrate acid n - (PHOSPHONOMETHYL) iminodia Cu00e9tico an adsorber with a noble metal to remove at least a portion ofL Solubilized noble metal and produce a Flow of Aqueous process treated with lower concentration of noble metal and a noble metal adsorption Medium comprising noble metal.Claim 30: a process to make a product N - (PHOSPHONOMETHYL) glycineCharacterized in that it comprises: a substrate oxidize acid n - (PHOSPHONOMETHYL) iminodiu00e1cetico System in an oxidation reactor in the presence of an Oxidation Catalyst comprising a noble metal to produce a mixture of reaction products including a noble metal Catalyst and Solution reaction products including Product N - (PHOSPHONOMETHYL Glycine Solub) and noble metalIlizado; precipitate Crystals of Product N - (PHOSPHONOMETHYL Glycine Solution) from the reaction products to produce a Slurry Product comprising Crystals Precipitated Product N - (PHOSPHONOMETHYL) glycine and mother Liquors containing noble metal Separating Solubilized; c Ristales Product N - (PHOSPHONOMETHYL glycine) of the product to give a Slurry CakeWet The Product N - (PHOSPHONOMETHYL glycine) and an aqueous Stream with lower Solid content that includes Waters mothers; and contacting at least a portion of the aqueous Stream with lower Solid content with a noble metal adsorption to separate at least a Portion of the noble metal from the flow of water with lower soluble Solids content and produceA flow of water treated with lower Solid content with a Lower concentration of noble metal and a noble metal adsorption Medium comprising noble metal.
机译:权利要求1:从包含水溶性增溶的贵金属的工艺流中回收贵金属的方法,该方法是在通过贵金属底物酸n-(PHOSPHONOMETHYL)i催化氧化而制备产物N-(磷酸膦酸)甘氨酸的过程中产生的Minodiac u00e9tico,该回收方法的特征在于,其包括:使至少一部分在该方法中产生的含水工艺流程接触,以通过贵金属底物酸n-(-)催化氧化而生成产物N-(膦酰基)甘氨酸。权利要求30:用贵金属吸附剂以除去至少一部分L溶解的贵金属并产生用较低浓度的贵金属和包含贵金属的贵金属吸附介质处理的水工艺流程。权利要求30:制备产物N-(膦酰基)甘氨酸的方法,其特征在于,它包括:底物氧化酸n-(膦酰基)亚胺二酸酯在氧化体系中在包含贵金属的氧化催化剂的存在下,反应器反应生成包括贵金属催化剂的反应产物和包括产物N-(膦酰基甘氨酸Solub)和贵金属Ilizado的溶液反应产物的混合物;从反应产物中沉淀出产物N-(膦酰基甘氨酸溶液)的晶体,以产生包含结晶沉淀产物N-(膦酰基)甘氨酸和含有贵金属的可溶解母液的浆状产物。 c将产品的R产品产品N-(磷酸甲基甘氨酸)制成浆状蛋糕。将产品N-(磷酸甲基甘氨酸)和固体含量较低的水性物流(包括沃特世的母亲)制成浆状蛋糕。使至少一部分具有较低固含量的水流与贵金属吸附接触,以将至少一部分贵金属与具有较低可溶性固含量的水流分离,并产生经较低固含量处理的水流。较低浓度的贵金属和包含贵金属的贵金属吸附介质。

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