POLYMER COMPLEX HAVING POLE AND METHOD OF CHEMICAL MODIFICATION OF POR INSIDE

摘要

In a polymer complex having a specific pore group B in which the characteristics of the environment in the pore are controlled by a specific substituent A, the pores of the pore group B are used as a reaction field after the formation of the polymer complex. The chemical modification method for the inner surface of the pores, which enables further control of the properties of the pore internal environment by converting the substituent A into another substituent, and very specific pores obtained by the chemical modification method Provided is a polymer complex having internal environmental characteristics. This is a method of chemically modifying the inner surface of at least one kind of pore group in a polymer complex having two or more kinds of pore groups composed of the same pores having a specific affinity for a guest molecule. The polymer complex includes an aromatic compound as a ligand having two or more coordination sites, a metal ion as a central metal, and a non-coordinating aromatic compound. A tertiary structure including a stacked structure in which a non-coordinating aromatic compound is inserted between aromatic compound ligands in a three-dimensional network structure formed by coordination of a ligand to the central metal ion. A non-coordinating aromatic compound having a specific substituent A at a specific position on its own aromatic ring. And the substituent A is specified from the two or more kinds of pore groups It is regularly arranged so as to face the inner surface of the pore group B, and guest molecules are included in the pores of the pore group B in which the substituent A is arranged. By reacting the guest molecule with the substituent A, the substituent A is converted into another substituent A ′, and the substituent A ′ is converted into the pores of the pore group B or other pore groups. A chemical modification method for an inner surface of a hole, which is arranged regularly so as to face the inner surface of the hole.