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Alloy containing rare earth element, production method thereof, magnetostrictive device, and magnetic refrigerant material
Alloy containing rare earth element, production method thereof, magnetostrictive device, and magnetic refrigerant material
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机译:含稀土元素的合金,其制造方法,磁致伸缩装置和磁性制冷剂材料
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摘要
A method for producing an RE-containing alloy represented by formula R(T1−xAx)13−y (wherein R represents Ce, etc.; T represents Fe, etc.; and A represents Al, etc; 0.05≦x≦0.2; and −1≦y≦1) including a melting step of melting alloy raw materials at 1,200 to 1,800° C.; and a solidification step of rapidly quenching the molten metal produced through the above step, to thereby form the first RE-containing alloy, wherein the solidification step is performed at a cooling rate of 102 to 104° C./second, as measured at least within a range of the temperature of the molten metal to 900° C.; and an RE-containing alloy, which is represented by a compositional formula of RrTtAa (wherein R and A represent the same meaning as above, T represents Fe, etc.; 5.0 at. %≦r≦6.8 at. %, 73.8 at. %≦t≦88.7 at. %, and 4.6 at. %≦a≦19.4 at. %) and has an alloy microstructure containing an NaZn13-type crystal structure in an amount of at least 85 mass % and α-Fe in an amount of 5-15 mass % inclusive.
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机译:一种由式R(T 1-x Sub> A x Sub>)13 -y Sub>表示的含RE合金的制造方法,其中R表示Ce T包括Fe等; T表示Fe等; A表示Al等;0.05≤x≤0.2;以及-1≤y≤1),包括在1200〜1800℃下熔融合金原料的熔融工序。快速固化通过上述步骤生产的熔融金属以形成第一含RE合金的固化步骤,其中固化步骤以10 2 Sup>至10 4℃/秒;和含RE的合金,其组成式为R r Sub> T t Sub> A a Sub>(其中R和A代表相同如上所述,T表示Fe等; 5.0原子%≤r≤6.8原子%,73.8原子%≤t≤88.7原子%,和4.6原子%≤a≤19.4原子%),具有合金微结构,其包含至少85质量%的NaZn 13 Sub>型晶体结构和包括5-15质量%的α-Fe。
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