首页> 外国专利> The thermoplastic composition in gel expansu00ecvel, process to produce a composition in gel flexu00ecvel expanded, and use of a composition in gel flexu00ecvel expanded

The thermoplastic composition in gel expansu00ecvel, process to produce a composition in gel flexu00ecvel expanded, and use of a composition in gel flexu00ecvel expanded

机译:凝胶中的热塑性组合物膨胀,制备以凝胶挠性膨胀的组合物的方法以及在凝胶挠性膨胀中的组合物的用途

摘要

The thermoplastic composition in gel expansu00ecvel, process to produce a composition in gel flexu00ecvel expanded, and use of a composition in gel flexible expanded.The invention relates to a composition for thermoplastic expandable gel comprising (a) a block copolymer comprising at least a block polymer derived from a compound of the monovila aromatic and at least one block of a conjugated diene polymer (B derivative; (b) a component Liquid, selected the group consisting of oils, solvents, plasticizers and dilators.They are compatible with the copolimero block mentioned above (a); (c) expandable thermoplastic particles by heat, gas or liquefied gas encapsulating expandable by heat; and (d) optionally a photo initiator.Characterized by the fact that the block copolymer (a) is a block copolymer which can be cross-linked by exposure to radiation and which has a content of compound of aromatic monovila 7 to 35% by weight, based on total polymer, an apparent molecular weight of total 50 to 1500 kg / mol and a The vinyl content in Block B of 10 to 80% by mol.In which the blocks B were optionally hydrogenated to a degree that at least 25% of the original etilu00eanica unsaturation is left. According to another aspect of the present invention, are provided with two processes to produce the composition gel flexible expanded.The invention also relates to the use of a composition in gel flexible expanded in automotive appliances, but also in applications such as cable filling, sealing reintroduzu00edvel electrical connections, vibration absorber, pressure relief, toys, cushion, Garr The therapeutic devices and orthopaedic and flexographic printing plates.
机译:凝胶膨胀中的热塑性组合物,制备凝胶弯曲中的组合物的方法以及该组合物在凝胶柔性中的用途。本发明涉及用于热塑性可膨胀凝胶的组合物,其包含(a)包含以下的嵌段共聚物:至少一种衍生自单壳芳族化合物和至少一个共轭二烯聚合物(B衍生物)的嵌段的嵌段聚合物;(b)液体组分,选自油,溶剂,增塑剂和扩张剂。 (a)上述共聚单体嵌段;(c)通过热,气体或液化气通过加热可囊封的可膨胀热塑性颗粒;以及(d)任选的光引发剂。可以通过暴露于辐射而发生交联的共聚物,其芳香族单基甲酸酯化合物的含量为总聚合物的7至35%(重量),基于总聚合物的表观分子量为50嵌段B中的乙烯基含量为10-80mol%至1500kg / mol。嵌段B中的乙烯基任选地被氢化至剩余至少25%的原始依蒂卡不饱和度的程度。根据本发明的另一个方面,提供了两种方法来生产凝胶柔性膨胀的组合物。本发明还涉及组合物在汽车电器中的凝胶柔性膨胀中的用途,以及在诸如电缆填充,密封的应用中reintroduz u00edvel电气连接,减震器,泄压装置,玩具,垫子,Garr治疗设备以及整形外科和苯胺印刷版。

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