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Fluorine ion liquids based on imidazole salts exhibiting high fluorophilicity

机译:基于咪唑盐的氟离子液体表现出高的亲氟性

摘要

preparation method of highly fluorofilnu00edch ionic liquids which contain a central imidazoliovou unitone highly fluorinated polyetherovu00fd chain of command and a highly fluorinated polyetherovu00fd or alkylovu00fd chain of command, while the total fluorine content is higher than 55%.their preparation is that responding imidazole with triflu00e1tem or nonaflu00e1tem alcohol containing highly fluorinated polyetherovu00fd or alkylovu00fd chain of command to produce fluorinated imidazole.as figure below responds again with triflu00e1tem or nonaflu00e1tem alcohol containing highly fluorinated polyetherovu00fd or alkylovu00fd chain of command to produce fluorinated imidazoliovu00e9 saltswhile at least one of the two fluorinated retezcu is polyetherovu00fd and figure below is possibly carried out metateze triflu00e1tovu00e9ho suitable inorganic salt such as ammonium anion - tetrafluorboru00e1t,ammonium), lithium bis) trifluormethylsulfonyl) - imide or sodium iodide.
机译:一种高氟离子液体的制备方法,该离子液体包含一个中央咪唑啉酮单酮,高度氟化的聚醚ov指令链和一个高度氟化的聚醚ov或烷基指令链,而总氟含量高于55%。制备方法是使咪唑与含有高度氟化的聚醚醚醇或烷烃的命令链的三氟甲磺酸或九氟醚醇反应生成氟代咪唑。 f00fd或alkalov u00fd命令链来产生氟化的咪唑啉ovu9e盐,而两个氟化的retezcu中的至少一个是聚醚醚ovuffd,下面的图可能是进行了metateze trifl u适合的无机盐,例如铵阴离子-四氟硼酸(铵,铵),双(三氟甲基磺酰基锂)-酰亚胺或碘化钠。

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