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PROCESS FOR THE PREPARATION OF 2,4-DIDEZOXYHEXOSES AND 2,4,6-TRIDEZOXYHEXOSES
PROCESS FOR THE PREPARATION OF 2,4-DIDEZOXYHEXOSES AND 2,4,6-TRIDEZOXYHEXOSES
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机译:2,4-二氧己酮和2,4,6-三重氧己酸的制备方法
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摘要
The invention relates to a process for the preparation of a 2,4-dideoxyhexose or a 2,4,6-trideoxyhexose from a substituted or unsubstituted carbonyl compound with at least 2 carbon atoms and at least one alpha-hydrogen atom and a substituted or unsubstituted aldehyde in the presence of an aldolase and water, the reaction between the substituted or unsubstituted carbonyl compound with at least 2 carbon atoms and at least one alpha-hydrogen atom and the substituted or unsubstituted aldehyde being carried out at a carbonyl concentration of at most 6 moles/l of reaction mixture and the final concentration of the 2,4-dideoxyhexose or the 2,4,6-trideoxyhexose being at least 2 mass % of the reaction mixture. The invention also relates to the use of a 2,4-dideoxyhexose or a 2,4,6-trideoxyhexose obtained by means of a process according to the invention in the preparation of a medicine, particularly in the preparation of a statine.
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