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A PROCESS FOR THE PREPARATION OF N-(PHOSPHONOMETHYL) GLYCINE OR A SALT OF N-(PHOSPHNOMETHYL)GLYCINE

机译:N-(膦酰基甲基)甘氨酸的制备方法或N-(膦酰基甲基)甘氨酸的盐的制备

摘要

A process for the preparation of N-(phosphonomethyl) glycine or a salt of N-(phosphonomethyl) iminodiacetic acid or a salt of N-(phosphonomethyl) iminodiacetic acid with an oxidation catalyst in a solution or slurry having a PH less than 7 and in the presence of oxygen, wherein: the catalyst comprises a carbon support having a noble metal and at least one promoter at a surface of the carbon support; the noble metal is selected from the group consisting of platinum, palladium, ruthenium, rhodium, iridium, silver, osminum, gold and combinations thereof; and the promoter is selected from the group consisting of tin, bismuth, lead, cadmium, magnesium, manganese, nickel, aluminum, cobalt, titanium, antimony, selenium, iron, rhenium, cerium, zinc, and zirconium.
机译:在PH值小于7的溶液或淤浆中用氧化催化剂制备N-(膦酰基甲基)甘氨酸或N-(膦酰基甲基)亚氨基二乙酸的盐或N-(膦酰基甲基)亚氨基二乙酸的盐的方法在氧气存在下,其中:催化剂包括具有贵金属的碳载体和在碳载体表面上的至少一种助催化剂;贵金属选自铂,钯,钌,铑,铱,银、,、金及其组合。促进剂选自锡,铋,铅,镉,镁,锰,镍,铝,钴,钛,锑,硒,铁,rh,铈,锌和锆。

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