首页> 外国专利> PROCESS FOR PRODUCING POLYALKYLENE TEREPHTHALATE, PROCESS FOR PRODUCING POLYALKYLENE TERRPHTHALATE MOLDING AND POLYALKYLENE TEREPHTHALATE MOLDING

PROCESS FOR PRODUCING POLYALKYLENE TEREPHTHALATE, PROCESS FOR PRODUCING POLYALKYLENE TERRPHTHALATE MOLDING AND POLYALKYLENE TEREPHTHALATE MOLDING

机译:聚对苯二甲酸乙二酯的制备方法,聚对苯二甲酸乙二酯模制和聚对苯二甲酸乙二酯模制的方法

摘要

The present invention provides a method of producing polyalkylene terephthalate, which comprises: introducing a prepolymer of polyalkylene terephthalate that is in a molten state comprising 70 mol% or more of ethylene terephthalate or 1,4-butylene terephthalate repeating units and having an intrinsic viscosity between 0.2 and 2 dl/g through a feed opening to a polymerization reactor; discharging the introduced prepolymer from holes of a perforated plate; and polymerizing the prepolymer under reduced pressure, while allowing the prepolymer to fall along the surface of a support that is open towards the outside at a temperature between the [crystalline melting point -10°C] of the prepolymer or higher and the [crystalline melting point + 30°C] of the prepolymer or lower under the conditions represented by a formula S1/S2 1, wherein S1 is the surface area of falling polyalkylene terephthalate, and S2 is the area where the support is in contact with polyalkylene terephthalate.
机译:本发明提供了一种生产聚对苯二甲酸亚烷基酯的方法,该方法包括:引入处于熔融态的聚对苯二甲酸亚烷基酯的预聚物,该预聚物包含70mol%或更多的对苯二甲酸乙二酯或1,4-对苯二甲酸丁二酯重复单元,并且其特性粘度为通过进料口至聚合反应器为0.2和2dl / g;从多孔板的孔中排出引入的预聚物;在使预聚物在[预聚物的[结晶熔点-10℃]以上且[结晶熔点]以下的温度下,沿着朝向外部开放的载体的表面落下的同时,使预聚物在减压下进行聚合。在由式S1 / S2> 1表示的条件下,预聚物的熔点为+ 30℃或更低;其中S1为下落的聚对苯二甲酸亚烷基酯的表面积,S2为载体与聚对苯二甲酸亚烷基酯接触的面积。

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