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A PROCESS FOR THE PALLADIUM-CATALYZED COUPLING OF TERMINAL ALKYNES WITH ARYL TOSYLATES
A PROCESS FOR THE PALLADIUM-CATALYZED COUPLING OF TERMINAL ALKYNES WITH ARYL TOSYLATES
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机译:端烷基与芳基甲苯磺酸盐的钯催化偶联反应过程
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摘要
The present invention relates to a process for the regioselective synthesisof compounds of the formula (I), wherein R1; R2; R3; R4; R5; J and W have the meaningsindicated in the claims. The present invention provides an efficient and generalpalladium-catalyzed coupling process for aryl tosylates with terminal alkynesto a wide variety of substituted, multifunctional aryl-1-alkynes of the formula(I) useful for the production of intermediates in the preparation for pharmaceuticals,diagnostic agents, liquid crystals, polymers, herbicides, fungicidals, nematicidals,parasiticides, insecticides, acaricides and arthropodicides.
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