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METHOD FOR PRODUCING POLYOLS AND THEIR APPLICATION FOR PRODUCING POLYURETHANES

机译:制备方法和在聚氨酯中的应用

摘要

1. The method of producing polyols of base-catalyzed addition of alkylene oxides containing at least 10 wt.% Ethylene oxide to multifunctional initiating compounds with hydrogen atoms active in the Cerevitin reaction in the presence of catalysts based on alkali metal hydroxides, alkali metal hydrides, alkaline earth metal hydrides, alkaline carboxylates metals, alkaline earth metal carboxylates or alkaline earth metal hydroxides, the concentration of which is from 0.004 to 0.5 wt.% in in terms of the amount of the final product, and the neutralization of the alkaline polymerization centers of the crude alkylene oxide addition product is carried out by the supply of sulfuric acid, which is implemented in such a way that to neutralize the amount of catalyst contained in the crude polymer, 66 to 100 mol% of the acid used in only the first stage of dissociation is used. ! 2. The method according to claim 1, wherein before or during the addition of alkylene oxides, 10 to 80 wt.% Triglycerides are added, calculated on the amount of the final product. ! 3. The use of polyols, which can be obtained according to claim 1 or 2, for the synthesis of polyurethanes.
机译:1.在基于碱金属氢氧化物,碱金属氢化物的催化剂的存在下,将由至少10重量%的环氧乙烷的碱催化加成的环氧烷烃加成到在Cerevitin反应中具有活性的氢原子的多官能引发化合物中的多元醇的制备方法碱金属氢化物,碱金属羧酸盐,碱土金属羧酸盐或碱土金属氢氧化物的浓度,以最终产物的量计,其浓度为0.004至0.5 wt。%,并且中和了碱性聚合反应粗环氧烷烃加成产物的中心是通过提供硫酸来实现的,硫酸的实施方式是中和粗聚合物中所含催化剂的量,其中仅在有机溶剂中所用酸的比例为66至100摩尔%。使用解离的第一阶段。 ! 2.根据权利要求1的方法,其中在添加环氧烷烃之前或之中,以最终产物的量计算,添加10至80重量%的甘油三酸酯。 ! 3.可以根据权利要求1或2获得的多元醇在合成聚氨酯中的用途。

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