, where R1=H, C1-C6 alkyl; R2=H, C1-C6 alkyl, C1-C6 alkoxy; R3=phenyl, naphthyl, 2-phenyl-1-ethenyl, thienyl, furyl, pyrrolyl, benzothiophenyl, benzofuranyl, indolyl, synthesis method thereof and use as compounds capable of photochemical generation of stable fluorophores of formula II, which can be used, for instance in information storage systems, particularly as photosensitive components of material for three-dimensional recording and storage of information. The invention also relates to novel 4,5-substituted-6-alkyl-1H-furo[3,4-c]carbazole-1,3(6H)diones of general formula II , where R1=H, C1-C6 alkyl; R2=H, C1-C6 alkyl, C1-C6 alkoxy; R4=H, R5=phenyl, R4, R5=benzo, naphtho, thieno, furo, pyrrolo, benzothieno, benzofuro, indolo, method for synthesis of said compounds and use as fluorophores.;EFFECT: obtaining novel compounds and possibility of using said compounds as fluorophores.;14 cl, 2 tbl, 8 ex"/> 4-SUBSTITUTED-3-(1-ALKYL-2-CHLORO-1H-INDOL-3-YL)FURAN-2,5-DIONES, SYNTHESIS METHOD THEREOF AND USE IN PHOTOCHEMICAL GENERATION OF STABLE FLUORESCENT COMPOUNDS AND 4,5-SUBSTITUTED-6-ALKYL-1H-FURO3,4-cCARBAZOLE-1,3(6H)-DIONES, SYNTHESIS METHOD THEREOF AND USE AS FLUOROPHORES
首页> 外国专利> 4-SUBSTITUTED-3-(1-ALKYL-2-CHLORO-1H-INDOL-3-YL)FURAN-2,5-DIONES, SYNTHESIS METHOD THEREOF AND USE IN PHOTOCHEMICAL GENERATION OF STABLE FLUORESCENT COMPOUNDS AND 4,5-SUBSTITUTED-6-ALKYL-1H-FURO3,4-cCARBAZOLE-1,3(6H)-DIONES, SYNTHESIS METHOD THEREOF AND USE AS FLUOROPHORES

4-SUBSTITUTED-3-(1-ALKYL-2-CHLORO-1H-INDOL-3-YL)FURAN-2,5-DIONES, SYNTHESIS METHOD THEREOF AND USE IN PHOTOCHEMICAL GENERATION OF STABLE FLUORESCENT COMPOUNDS AND 4,5-SUBSTITUTED-6-ALKYL-1H-FURO3,4-cCARBAZOLE-1,3(6H)-DIONES, SYNTHESIS METHOD THEREOF AND USE AS FLUOROPHORES

机译:4-取代-3-(1-烷基-2-氯-1H-吲哚-3-基)呋喃-2,5-二酮的合成方法及其在稳定的荧光化合物和4,5-取代的光化学反应中的应用6-烷基-1H-呋喃[3,4-c]咔唑-1,3(6H)-二酮的合成方法及其用作荧光粉的用途

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to novel compounds, specifically to 4-substituted-3-(1-alkyl-2-chloro-1H-indol-3-yl)furan-2,5-diones of general formula I , where R1=H, C1-C6 alkyl; R2=H, C1-C6 alkyl, C1-C6 alkoxy; R3=phenyl, naphthyl, 2-phenyl-1-ethenyl, thienyl, furyl, pyrrolyl, benzothiophenyl, benzofuranyl, indolyl, synthesis method thereof and use as compounds capable of photochemical generation of stable fluorophores of formula II, which can be used, for instance in information storage systems, particularly as photosensitive components of material for three-dimensional recording and storage of information. The invention also relates to novel 4,5-substituted-6-alkyl-1H-furo[3,4-c]carbazole-1,3(6H)diones of general formula II , where R1=H, C1-C6 alkyl; R2=H, C1-C6 alkyl, C1-C6 alkoxy; R4=H, R5=phenyl, R4, R5=benzo, naphtho, thieno, furo, pyrrolo, benzothieno, benzofuro, indolo, method for synthesis of said compounds and use as fluorophores.;EFFECT: obtaining novel compounds and possibility of using said compounds as fluorophores.;14 cl, 2 tbl, 8 ex
机译:发明领域本发明涉及新型化合物,特别是通式I的4-取代的-3-(1-烷基-2-氯-1H-吲哚-3-基)呋喃-2,5-二酮。图片文件=“ 00000001.GIF” he =“ 49” imgContent =“未定义” imgFormat =“ GIF” wi =“ 47” />,其中R 1 = H,C 1 < / Sub> -C 6 烷基; R 2 = H,C 1 -C 6 烷基,C 1 -C 6 烷氧基; R 3 =苯基,萘基,2-苯基-1-乙烯基,噻吩基,呋喃基,吡咯基,苯并噻吩基,苯并呋喃基,吲哚基,它们的合成方法以及用作能够光化学生成式I的稳定荧光团的化合物II,其可以例如在信息存储系统中使用,特别是作为用于信息的三维记录和存储的材料的光敏部件。本发明还涉及通式II的新型4,5-取代的6-烷基-1H-呋喃并[3,4-c]咔唑-1,3(6H)二酮<图像文件=“ 00000002.GIF” “ 48” imgContent =“ undefined” imgFormat =“ GIF” wi =“ 51” />,其中R1 = H,C1-C6烷基; R2 = H,C1-C6烷基,C1-C6烷氧基; R 4 = H,R 5 =苯基,R 4,R 5 =苯并,萘,噻吩并,呋喃,吡咯并,苯并噻吩并,苯并呋喃,吲哚并,所述化合物的合成方法和用作荧光团。效果:获得新化合物并有可能使用所述化合物化合物;荧光团; 14 cl,2 tbl,8 ex

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